Chirality Enhancement Using Fabry-Pérot-Like Cavity

Abstract

Chiral molecules that do not superimpose on their mirror images are the foundation of all life forms on earth. Chiral molecules exhibit chiroptical responses, i.e., they have different electromagnetic responses to light of different circular polarizations. However, chiroptical responses in natural materials, such as circular dichroism and optical rotation dispersion, are intrinsically small because the size of a chiral molecule is significantly shorter than the wavelength of electromagnetic wave. Conventional technology for enhancing chiroptical signal entails demanding requirements on precise alignment of the chiral molecules to certain nanostructures, which however only leads to a limited performance. Herein, we show a new approach towards enhancement of chiroptical effects through a Fabry-Pérot (FP) cavity formed by two handedness-preserving metamirrors operating in the GHz region. We experimentally show that the FP cavity resonator can enhance the optical activity of the chiral molecule by an order of magnitude. Our approach may pave the way towards state-of-the-art chiral sensing applications.