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- Publisher Website: 10.1016/0277-5387(96)00231-8
- Scopus: eid_2-s2.0-0001321637
- WOS: WOS:A1996VM01700035
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Article: Synthesis and X-ray crystal structures of [Ph2PMe2][(η5-C5H4But)2Li] and [(η5-C5H4But)2Yb(Cl)CH2P(Me)Ph2]
| Title | Synthesis and X-ray crystal structures of [Ph2PMe2][(η5-C5H4But)2Li] and [(η5-C5H4But)2Yb(Cl)CH2P(Me)Ph2] |
|---|---|
| Authors | |
| Issue Date | 1996 |
| Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
| Citation | Polyhedron, 1996, v. 15 n. 24, p. 4593-4597 How to Cite? |
| Abstract | The interaction of [(η5-C5H4But)2YbCl · LiCl] with one equivalent of Li[(CH2) (CH2)PPh2] in tetrahydrofuran gave [Ph2PMe2][(η5-C5H4But)2Li] (1) and [(η5-C5H4But)2Yb(Cl)CH2P(Me)Ph2] (2) in 10% and 30% yields, respectively. 1 could also be prepared in 70% yield from the reaction of [Ph2PMe2][CF3SO3] with two equivalents of (C5H4But)Li. Both compounds have been fully characterized by analytical, spectroscopic and X-ray diffraction methods. The solid state structure of 1 reveals a sandwich structure for the [(η5-C5H4But)2Li]− anion. |
| Persistent Identifier | http://hdl.handle.net/10722/69535 |
| ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.379 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Wong, WK | en_HK |
| dc.contributor.author | Zhang, L | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.contributor.author | Xue, F | en_HK |
| dc.contributor.author | Mak, TCW | en_HK |
| dc.date.accessioned | 2010-09-06T06:14:34Z | - |
| dc.date.available | 2010-09-06T06:14:34Z | - |
| dc.date.issued | 1996 | en_HK |
| dc.identifier.citation | Polyhedron, 1996, v. 15 n. 24, p. 4593-4597 | en_HK |
| dc.identifier.issn | 0277-5387 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69535 | - |
| dc.description.abstract | The interaction of [(η5-C5H4But)2YbCl · LiCl] with one equivalent of Li[(CH2) (CH2)PPh2] in tetrahydrofuran gave [Ph2PMe2][(η5-C5H4But)2Li] (1) and [(η5-C5H4But)2Yb(Cl)CH2P(Me)Ph2] (2) in 10% and 30% yields, respectively. 1 could also be prepared in 70% yield from the reaction of [Ph2PMe2][CF3SO3] with two equivalents of (C5H4But)Li. Both compounds have been fully characterized by analytical, spectroscopic and X-ray diffraction methods. The solid state structure of 1 reveals a sandwich structure for the [(η5-C5H4But)2Li]− anion. | - |
| dc.language | eng | en_HK |
| dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly | en_HK |
| dc.relation.ispartof | Polyhedron | en_HK |
| dc.title | Synthesis and X-ray crystal structures of [Ph2PMe2][(η5-C5H4But)2Li] and [(η5-C5H4But)2Yb(Cl)CH2P(Me)Ph2] | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=15&issue=24&spage=4593&epage=4597&date=1996&atitle=Synthesis+and+x-ray+crystal+structures+of+[Ph2PMe2][h5=V5H4But)2Li]+and+[(h5-C5H4But)2Yb(Cl)CH2P(Me)Ph2] | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.doi | 10.1016/0277-5387(96)00231-8 | - |
| dc.identifier.scopus | eid_2-s2.0-0001321637 | - |
| dc.identifier.hkuros | 21852 | en_HK |
| dc.identifier.volume | 15 | - |
| dc.identifier.issue | 24 | - |
| dc.identifier.spage | 4593 | - |
| dc.identifier.epage | 4597 | - |
| dc.identifier.isi | WOS:A1996VM01700035 | - |
| dc.publisher.place | Netherlands | - |
| dc.identifier.issnl | 0277-5387 | - |