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Article: Synthesis and X-ray crystal structure of cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)]
| Title | Synthesis and X-ray crystal structure of cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)] |
|---|---|
| Authors | |
| Issue Date | 1995 |
| Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
| Citation | Polyhedron, 1995, v. 14 n. 12, p. 1695-1697 How to Cite? |
| Abstract | The interaction of (Ph2PN)C(Ph)[N(SiMe3)2] with one equivalent of C7H8Cr(CO)4 in diethyl ether gave cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)] in good yield. The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction methods. The NH proton of the bidentate iminophosphine ligand undergoes facile deuterium exchange with D2O at ambient temperature. A 1,3-silyl shift mechanism has been proposed for the formation of the product. |
| Persistent Identifier | http://hdl.handle.net/10722/69517 |
| ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.379 |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Wong, WK | en_HK |
| dc.contributor.author | Jiang, T | en_HK |
| dc.contributor.author | Kwong, DWJ | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.date.accessioned | 2010-09-06T06:14:23Z | - |
| dc.date.available | 2010-09-06T06:14:23Z | - |
| dc.date.issued | 1995 | en_HK |
| dc.identifier.citation | Polyhedron, 1995, v. 14 n. 12, p. 1695-1697 | en_HK |
| dc.identifier.issn | 0277-5387 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69517 | - |
| dc.description.abstract | The interaction of (Ph2PN)C(Ph)[N(SiMe3)2] with one equivalent of C7H8Cr(CO)4 in diethyl ether gave cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)] in good yield. The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction methods. The NH proton of the bidentate iminophosphine ligand undergoes facile deuterium exchange with D2O at ambient temperature. A 1,3-silyl shift mechanism has been proposed for the formation of the product. | - |
| dc.language | eng | en_HK |
| dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly | en_HK |
| dc.relation.ispartof | Polyhedron | en_HK |
| dc.title | Synthesis and X-ray crystal structure of cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)] | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=14&issue=2&spage=1695&epage=1697&date=1995&atitle=Synthesis+and+X-ray+crystal+structure+of+cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)] | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1016/0277-5387(95)00117-B | - |
| dc.identifier.scopus | eid_2-s2.0-58149364559 | - |
| dc.identifier.hkuros | 14698 | en_HK |
| dc.identifier.volume | 14 | - |
| dc.identifier.issue | 12 | - |
| dc.identifier.spage | 1695 | - |
| dc.identifier.epage | 1697 | - |
| dc.publisher.place | Netherlands | - |
| dc.identifier.issnl | 0277-5387 | - |