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Article: Synthesis, X-ray crystal structure and magnetic properties of a new binuclear complex derived from a pentadentate Schiff base ligand
Title | Synthesis, X-ray crystal structure and magnetic properties of a new binuclear complex derived from a pentadentate Schiff base ligand |
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Authors | |
Issue Date | 2003 |
Publisher | NISCAIR. The Journal's web site is located at http://www.niscair.res.in/sciencecommunication/researchjournals/rejour/ijca/ijca0.asp |
Citation | Indian Journal Of Chemistry - Section A Inorganic, Physical, Theoretical And Analytical Chemistry, 2003, v. 42 n. 5, p. 1004-1007 How to Cite? |
Abstract | A new binuclear nickel(II) complex [Ni2L2(N3)2](ClO4)2 1 has been synthesized and characterized. The structure of 1 has been determined by single crystal X-ray diffraction studies. The structure analysis indicates that each nickel(II) centre is in a distorted octahedral (NiN6) coordination environment with three nitrogen atoms from one and two nitrogen atoms from other pentadentate ligand and the last one from terminal azido ion. Variable-temperature magnetic susceptibility measurements of the compound 1 showed no evidence of magnetic exchange between two nickel(II) centres. This is consistent with the structure with large Ni...Ni distance (5.865(1) Å) and absence of any suitable bridging ligand capable of transmitting this type of interactions. |
Persistent Identifier | http://hdl.handle.net/10722/69494 |
ISSN | 2022 Impact Factor: 0.4 2023 SCImago Journal Rankings: 0.129 |
References |
DC Field | Value | Language |
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dc.contributor.author | Deoghoria, S | en_HK |
dc.contributor.author | Wong, WT | en_HK |
dc.contributor.author | Chandra, SK | en_HK |
dc.date.accessioned | 2010-09-06T06:14:10Z | - |
dc.date.available | 2010-09-06T06:14:10Z | - |
dc.date.issued | 2003 | en_HK |
dc.identifier.citation | Indian Journal Of Chemistry - Section A Inorganic, Physical, Theoretical And Analytical Chemistry, 2003, v. 42 n. 5, p. 1004-1007 | en_HK |
dc.identifier.issn | 0376-4710 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69494 | - |
dc.description.abstract | A new binuclear nickel(II) complex [Ni2L2(N3)2](ClO4)2 1 has been synthesized and characterized. The structure of 1 has been determined by single crystal X-ray diffraction studies. The structure analysis indicates that each nickel(II) centre is in a distorted octahedral (NiN6) coordination environment with three nitrogen atoms from one and two nitrogen atoms from other pentadentate ligand and the last one from terminal azido ion. Variable-temperature magnetic susceptibility measurements of the compound 1 showed no evidence of magnetic exchange between two nickel(II) centres. This is consistent with the structure with large Ni...Ni distance (5.865(1) Å) and absence of any suitable bridging ligand capable of transmitting this type of interactions. | en_HK |
dc.language | eng | en_HK |
dc.publisher | NISCAIR. The Journal's web site is located at http://www.niscair.res.in/sciencecommunication/researchjournals/rejour/ijca/ijca0.asp | en_HK |
dc.relation.ispartof | Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry | en_HK |
dc.title | Synthesis, X-ray crystal structure and magnetic properties of a new binuclear complex derived from a pentadentate Schiff base ligand | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
dc.identifier.authority | Wong, WT=rp00811 | en_HK |
dc.description.nature | published_or_final_version | - |
dc.identifier.scopus | eid_2-s2.0-0038110715 | en_HK |
dc.identifier.hkuros | 82661 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0038110715&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 42 | en_HK |
dc.identifier.issue | 5 | en_HK |
dc.identifier.spage | 1004 | en_HK |
dc.identifier.epage | 1007 | en_HK |
dc.publisher.place | India | en_HK |
dc.identifier.scopusauthorid | Deoghoria, S=6506275529 | en_HK |
dc.identifier.scopusauthorid | Wong, WT=7403973084 | en_HK |
dc.identifier.scopusauthorid | Chandra, SK=7401671646 | en_HK |
dc.identifier.issnl | 0376-4710 | - |