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Article: Synthesis of rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime
| Title | Synthesis of rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime 線型1,2-鄰二萘醌-1-肟(1-nqo)釕配合物的合成 |
|---|---|
| Authors | |
| Keywords | Ruthenium (釕) 1; 2-naphthoquinone-1-oxime (1; 2-鄰二萘醌-1-肟) Decarbonylated substitution (羰基取代) |
| Issue Date | 2002 |
| Publisher | Science Press (科學出版社). The Journal's web site is located at http://hxxb.periodicals.net.cn/default.html |
| Citation | Acta Chimica Sinica, 2002, v. 60 n. 6, p. 1058-1064 How to Cite? 化學學報, 2002, v. 60 n. 6, p. 1058-1064 How to Cite? |
| Abstract | By decarbonylated substitution reactions, rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime (1-nqo) are synthesized as trans-,cis- and cis-, cis-[Ru(1-nqo) 2(CO)(spy)] (3) and (4) which containing C 16 long alkyl chains in the molecules, cis-,cis-[Ru(1-nqo) 2(CO)(opy)] (5) and trans-,trans-[Ru(1-nqo) 2(opy) 2] (6) which containing C 18 long alkyl chains in the molecules. The complexes are characterized by IR, FAB MS, 1H- 1H COSY NMR and UV-visible spectra. 報道了含C1 6長碳鏈線型 1,2 鄰二萘醌 1 肟 (1 nqo)釕配合物trans ,cis 及cis ,cis [Ru(1 nqo) 2 (CO) (spy) ](3)及 (4 ) ,含C1 8長碳鏈線型 1 nqo釕配合物cis ,cis [Ru(1 nqo) 2 (CO) (opy) ](5 ) ,trans ,trans [Ru(1 nqo) 2 (opy) 2 ](6 )的合成 .利用紅外、FAB質譜、核磁共振氫譜及紫外 -可見吸收光譜表征配合物的結構 ,利用1 H 1 H偶合二維核磁技術對核磁共振峰進行指認 |
| Persistent Identifier | http://hdl.handle.net/10722/69283 |
| ISSN | 2021 Impact Factor: 2.789 2020 SCImago Journal Rankings: 0.565 |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Liu, XX | en_HK |
| dc.contributor.author | Sun, K | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.contributor.author | Niu, JJ | en_HK |
| dc.contributor.author | Zhang, BY | en_HK |
| dc.date.accessioned | 2010-09-06T06:12:14Z | - |
| dc.date.available | 2010-09-06T06:12:14Z | - |
| dc.date.issued | 2002 | en_HK |
| dc.identifier.citation | Acta Chimica Sinica, 2002, v. 60 n. 6, p. 1058-1064 | en_HK |
| dc.identifier.citation | 化學學報, 2002, v. 60 n. 6, p. 1058-1064 | - |
| dc.identifier.issn | 0567-7351 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/69283 | - |
| dc.description.abstract | By decarbonylated substitution reactions, rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime (1-nqo) are synthesized as trans-,cis- and cis-, cis-[Ru(1-nqo) 2(CO)(spy)] (3) and (4) which containing C 16 long alkyl chains in the molecules, cis-,cis-[Ru(1-nqo) 2(CO)(opy)] (5) and trans-,trans-[Ru(1-nqo) 2(opy) 2] (6) which containing C 18 long alkyl chains in the molecules. The complexes are characterized by IR, FAB MS, 1H- 1H COSY NMR and UV-visible spectra. | - |
| dc.description.abstract | 報道了含C1 6長碳鏈線型 1,2 鄰二萘醌 1 肟 (1 nqo)釕配合物trans ,cis 及cis ,cis [Ru(1 nqo) 2 (CO) (spy) ](3)及 (4 ) ,含C1 8長碳鏈線型 1 nqo釕配合物cis ,cis [Ru(1 nqo) 2 (CO) (opy) ](5 ) ,trans ,trans [Ru(1 nqo) 2 (opy) 2 ](6 )的合成 .利用紅外、FAB質譜、核磁共振氫譜及紫外 -可見吸收光譜表征配合物的結構 ,利用1 H 1 H偶合二維核磁技術對核磁共振峰進行指認 | - |
| dc.language | eng | en_HK |
| dc.publisher | Science Press (科學出版社). The Journal's web site is located at http://hxxb.periodicals.net.cn/default.html | - |
| dc.relation.ispartof | Acta Chimica Sinica | en_HK |
| dc.relation.ispartof | 化學學報 | - |
| dc.subject | Ruthenium (釕) | - |
| dc.subject | 1; 2-naphthoquinone-1-oxime (1; 2-鄰二萘醌-1-肟) | - |
| dc.subject | Decarbonylated substitution (羰基取代) | - |
| dc.title | Synthesis of rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime | en_HK |
| dc.title | 線型1,2-鄰二萘醌-1-肟(1-nqo)釕配合物的合成 | - |
| dc.type | Article | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.hkuros | 76338 | en_HK |
| dc.identifier.volume | 60 | - |
| dc.identifier.issue | 6 | - |
| dc.identifier.spage | 1058 | - |
| dc.identifier.epage | 1064 | - |
| dc.publisher.place | Beijing (北京) | - |
| dc.identifier.issnl | 0567-7351 | - |