Self-assembled functional molecular materials for optoelectronic applications

Abstract

There has been a growing interest to develop functional organic and organometallic materials in nano-scale by self assembly reactions as these materials could have unique electronic properties and applications. We have found that functionalized organometallic nano-wires which the formations are directed by weak Pt⋯Pt interactions along the dimension of the aggregates can be readily obtained by self-assembly reactions. These platinum(II) nano-wires exhibit interesting photophysical properties, vapochromic behavior, and could be used in the fabrication of organic (light-emitting) field-effect transistors.1,2 We have also found that thermally stable coordination polymers (with decomposition temperature up to 490°C), employing Zn 2+ as template metal ion and Schiff base or terpyridine as repeating chelating units, could be easily synthesized by self-assembly reactions. 3,4 These zinc (II) coordination polymers exhibit intense blue to green photoluminescence, and their thin-film samples have PL quantum yields up to 0.55. Polymer light-emitting devices (PLEDs) employing these coordination polymers as emitters give blue and green EL with turn-on voltage as low as 5 V and maximum efficiency up to 2.0 cd A-1. © 2009 Materials Research Society.