Correlated cosmogenic W and Os isotopic variations in Carbo and implications for Hf-W chronology

Abstract

An obstacle for establishing the chronology of iron meteorite formation using ¹⁸²Hf-¹⁸²W systematics (t<inf>1/2</inf>=8.9Myr) is to find proper neutron fluence monitors to correct for cosmic ray modification of W isotopic composition. Recent studies showed that siderophile elements such as Pt and Os could serve such a purpose. To test and calibrate these neutron dosimeters, the isotopic compositions of W and Os were measured in a slab of the IID iron meteorite Carbo. This slab has a well-characterized noble gas depth profile reflecting different degrees of shielding to cosmic rays. The results show that W and Os isotopic ratios correlate with distance from the pre-atmospheric center. Negative correlations, barely resolved within error, were found between ε¹⁹⁰Os-ε¹⁸⁹Os and ε¹⁸⁶Os-ε¹⁸⁹Os with slopes of -0.64±0.45 and -1.8(+1.9/-2.1), respectively. These Os isotope correlations broadly agree with model predictions for capture of secondary neutrons produced by cosmic ray irradiation and results reported previously for other groups of iron meteorites. Correlations were also found between ε¹⁸²W-ε¹⁸⁹Os (slope=1.02±0.37) and ε¹⁸²W-ε¹⁹⁰Os (slope=-1.38±0.58). Intercepts of these two correlations yield pre-exposure ε¹⁸²W values of -3.32±0.51 and -3.62±0.23, respectively (weighted average ε¹⁸²W=-3.57±0.21). This value relies on a large extrapolation leading to a large uncertainty but gives a metal-silicate segregation age of -0.5±2.4Myr after formation of the solar system. Combining the iron meteorite measurements with simulations of cosmogenic effects in iron meteorites, equations are presented to calculate and correct for cosmogenic effects on ¹⁸²W using Os isotopes.