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- Publisher Website: 10.1039/d2cc03002k
- Scopus: eid_2-s2.0-85133621207
- PMID: 35762347
- WOS: WOS:000817692200001
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Article: Oxidative C-O bond cleavage of dihydroxybenzenes and conversion of coordinated cyanide to carbon monoxide using a luminescent Os(vi) cyanonitrido complex
| Title | Oxidative C-O bond cleavage of dihydroxybenzenes and conversion of coordinated cyanide to carbon monoxide using a luminescent Os(vi) cyanonitrido complex |
|---|---|
| Authors | |
| Issue Date | 20-Jun-2022 |
| Publisher | Royal Society of Chemistry |
| Citation | Chemical Communications, 2022, v. 58, n. 57, p. 7988-7991 How to Cite? |
| Abstract | The photoreactions of a luminescent osmium(vi) nitrido complex, [OsVI(N)(L)(CN)3]− (OsN, HL = 2-(2-hydroxy-5-nitrophenyl)benzoxazole), with catechol (H2Cat) and hydroquinone (H2Q) lead to the cleavage of strong C-OH bonds (ca. 120 kcal mol−1) of the dihydroxybenzenes with concomitant conversion of the coordinated cyanide to carbon monoxide. |
| Persistent Identifier | http://hdl.handle.net/10722/357923 |
| ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 1.133 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Xiang, Jing | - |
| dc.contributor.author | Zhu, Jiang | - |
| dc.contributor.author | Zhou, Miaomiao | - |
| dc.contributor.author | Liu, Lu Lu | - |
| dc.contributor.author | Wang, Li Xin | - |
| dc.contributor.author | Peng, Min | - |
| dc.contributor.author | Hou, Bi Shun | - |
| dc.contributor.author | Yiu, Shek Man | - |
| dc.contributor.author | To, Wai Pong | - |
| dc.contributor.author | Che, Chi Ming | - |
| dc.contributor.author | Lau, Kai Chung | - |
| dc.contributor.author | Lau, Tai Chu | - |
| dc.date.accessioned | 2025-07-23T00:30:44Z | - |
| dc.date.available | 2025-07-23T00:30:44Z | - |
| dc.date.issued | 2022-06-20 | - |
| dc.identifier.citation | Chemical Communications, 2022, v. 58, n. 57, p. 7988-7991 | - |
| dc.identifier.issn | 1359-7345 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/357923 | - |
| dc.description.abstract | The photoreactions of a luminescent osmium(vi) nitrido complex, [OsVI(N)(L)(CN)3]− (OsN, HL = 2-(2-hydroxy-5-nitrophenyl)benzoxazole), with catechol (H2Cat) and hydroquinone (H2Q) lead to the cleavage of strong C-OH bonds (ca. 120 kcal mol−1) of the dihydroxybenzenes with concomitant conversion of the coordinated cyanide to carbon monoxide. | - |
| dc.language | eng | - |
| dc.publisher | Royal Society of Chemistry | - |
| dc.relation.ispartof | Chemical Communications | - |
| dc.title | Oxidative C-O bond cleavage of dihydroxybenzenes and conversion of coordinated cyanide to carbon monoxide using a luminescent Os(vi) cyanonitrido complex | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1039/d2cc03002k | - |
| dc.identifier.pmid | 35762347 | - |
| dc.identifier.scopus | eid_2-s2.0-85133621207 | - |
| dc.identifier.volume | 58 | - |
| dc.identifier.issue | 57 | - |
| dc.identifier.spage | 7988 | - |
| dc.identifier.epage | 7991 | - |
| dc.identifier.eissn | 1364-548X | - |
| dc.identifier.isi | WOS:000817692200001 | - |
| dc.identifier.issnl | 1359-7345 | - |