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- Publisher Website: 10.1002/zaac.202000151
- Scopus: eid_2-s2.0-85086131482
- WOS: WOS:000538642300001
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Article: Unusually large 254 Atoms Counter-Ion for 5 Atoms [Ge5 ]2– Cluster
| Title | Unusually large 254 Atoms Counter-Ion for 5 Atoms [Ge<inf>5</inf>]<sup>2–</sup> Cluster |
|---|---|
| Authors | |
| Keywords | 18-Crown-6 Alkoxide Cluster Heteronuclear Niobium Zintl phases |
| Issue Date | 2020 |
| Citation | Zeitschrift fur Anorganische und Allgemeine Chemie, 2020, v. 646, n. 14, p. 1030-1033 How to Cite? |
| Abstract | Abstract. With the attempt to synthesize Nb-enclosed germanium Zintl cluster ion in ethylenediamine (en) / toluene solution, the reaction of K4Ge9/Na4Ge9 with Nb(mes)2 (mes = mesitylene) gives unexpected 18-crown-6 cleavage product of [K14Na2(NbO2)2(C8H16O5)8](Ge5) (en)·solv in the form of very air-sensitive, light-brown, plate-like crystals. This unique compound crystallizes in monoclinic Pn (No. 7) space group, the cleavage of crown linked the 14 potassium, 2 sodium, and 2 niobium atoms into the bulky 2+ charged cation, which balances the [Ge5]2– anion. This compound represents the rare example of heteronuclear metal alkoxide / Zintl ion hybrid. |
| Persistent Identifier | http://hdl.handle.net/10722/355418 |
| ISSN | 2023 Impact Factor: 1.1 2023 SCImago Journal Rankings: 0.274 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Zavalij, Peter Y. | - |
| dc.contributor.author | Li, Ai Min | - |
| dc.contributor.author | Eichhorn, Bryan W. | - |
| dc.date.accessioned | 2025-04-08T03:40:36Z | - |
| dc.date.available | 2025-04-08T03:40:36Z | - |
| dc.date.issued | 2020 | - |
| dc.identifier.citation | Zeitschrift fur Anorganische und Allgemeine Chemie, 2020, v. 646, n. 14, p. 1030-1033 | - |
| dc.identifier.issn | 0044-2313 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/355418 | - |
| dc.description.abstract | Abstract. With the attempt to synthesize Nb-enclosed germanium Zintl cluster ion in ethylenediamine (en) / toluene solution, the reaction of K4Ge9/Na4Ge9 with Nb(mes)2 (mes = mesitylene) gives unexpected 18-crown-6 cleavage product of [K14Na2(NbO2)2(C8H16O5)8](Ge5) (en)·solv in the form of very air-sensitive, light-brown, plate-like crystals. This unique compound crystallizes in monoclinic Pn (No. 7) space group, the cleavage of crown linked the 14 potassium, 2 sodium, and 2 niobium atoms into the bulky 2+ charged cation, which balances the [Ge5]2– anion. This compound represents the rare example of heteronuclear metal alkoxide / Zintl ion hybrid. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Zeitschrift fur Anorganische und Allgemeine Chemie | - |
| dc.subject | 18-Crown-6 | - |
| dc.subject | Alkoxide | - |
| dc.subject | Cluster | - |
| dc.subject | Heteronuclear | - |
| dc.subject | Niobium | - |
| dc.subject | Zintl phases | - |
| dc.title | Unusually large 254 Atoms Counter-Ion for 5 Atoms [Ge<inf>5</inf>]<sup>2–</sup> Cluster | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/zaac.202000151 | - |
| dc.identifier.scopus | eid_2-s2.0-85086131482 | - |
| dc.identifier.volume | 646 | - |
| dc.identifier.issue | 14 | - |
| dc.identifier.spage | 1030 | - |
| dc.identifier.epage | 1033 | - |
| dc.identifier.eissn | 1521-3749 | - |
| dc.identifier.isi | WOS:000538642300001 | - |