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- Publisher Website: 10.1016/j.chempr.2025.102495
- Scopus: eid_2-s2.0-86000511302
- WOS: WOS:001449300000001
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Article: Manipulating alkoxy radicals for site- and enantioselective C–H oxidation
| Title | Manipulating alkoxy radicals for site- and enantioselective C–H oxidation |
|---|---|
| Authors | |
| Issue Date | 13-Mar-2025 |
| Publisher | Cell Press |
| Citation | Chem, 2025, v. 11, n. 3 How to Cite? |
| Abstract | Using C–H substrates as limiting reagents to achieve non-directed C–H activation with high selectivity has been a long-standing challenge in organic synthesis. Recently in Nature Catalysis, Liu et al. introduce a biomimetic catalytic system that employs Cu(II)-bound tert-butoxy radicals for site-selective C–H abstraction, enabling highly efficient asymmetric C(sp3)–H oxidation. |
| Persistent Identifier | http://hdl.handle.net/10722/355259 |
| ISSN | 2023 SCImago Journal Rankings: 6.556 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | He, Jian | - |
| dc.contributor.author | Che, Chi-Ming | - |
| dc.date.accessioned | 2025-04-01T00:35:16Z | - |
| dc.date.available | 2025-04-01T00:35:16Z | - |
| dc.date.issued | 2025-03-13 | - |
| dc.identifier.citation | Chem, 2025, v. 11, n. 3 | - |
| dc.identifier.issn | 2451-9308 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/355259 | - |
| dc.description.abstract | <p>Using C–H substrates as limiting reagents to achieve non-directed C–H activation with high selectivity has been a long-standing challenge in organic synthesis. Recently in <em>Nature Catalysis</em>, Liu et al. introduce a biomimetic catalytic system that employs Cu(II)-bound <em>tert</em>-butoxy radicals for site-selective C–H abstraction, enabling highly efficient asymmetric C(sp<sup>3</sup>)–H oxidation.</p> | - |
| dc.language | eng | - |
| dc.publisher | Cell Press | - |
| dc.relation.ispartof | Chem | - |
| dc.title | Manipulating alkoxy radicals for site- and enantioselective C–H oxidation | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1016/j.chempr.2025.102495 | - |
| dc.identifier.scopus | eid_2-s2.0-86000511302 | - |
| dc.identifier.volume | 11 | - |
| dc.identifier.issue | 3 | - |
| dc.identifier.eissn | 2451-9294 | - |
| dc.identifier.isi | WOS:001449300000001 | - |
| dc.identifier.issnl | 2451-9294 | - |