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Article: Highly Reversible O2 Conversions by Coupling LiO2 Intermediate through a Dual-Site Catalyst in Li-O2 Batteries
Title | Highly Reversible O<inf>2</inf> Conversions by Coupling LiO<inf>2</inf> Intermediate through a Dual-Site Catalyst in Li-O<inf>2</inf> Batteries |
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Authors | |
Keywords | iodosylbenzene Li-O batteries 2 LiO intermediates 2 soluble catalysts |
Issue Date | 2020 |
Citation | Advanced Energy Materials, 2020, v. 10, n. 38, article no. 2001592 How to Cite? |
Abstract | The reduction of O2 to solid Li2O2 on discharge and the reverse oxidation of Li2O2 to O2 on recharge are the essential processes to determine the performance of Li-O2 batteries. The discovery of effective catalysts with a favorable Li2O2 formation/decomposition mechanism is vital for the development of high-performance Li-O2 batteries. Here, a soluble catalyst of iodosylbenzene (PhIO) that can offer a highly reversible O2 conversion is reported for the first time. Benefiting from its ability to capture and couple the LiO2 intermediate, which is endowed by its polarized I3+=O2− bond where the I atom and O atom can serve as a Lewis acidic site and basic site (dual site) to interact with O2− and Li+, respectively, the formation and decomposition of Li2O2 by a one-electron pathway can be effectively promoted, thus greatly improving the electrode surface passivation issue and the reaction kinetics. In addition, the side reactions caused by the traditional high-reactive LiO2 intermediate can also be effectively suppressed by forming a series of low-reactive intermediates (LiO2-3PhIO, (LiO2)2-4PhIO, and Li2O2-4PhIO) instead. Consequently, the PhIO-catalyzed Li–O2 batteries exhibit a low overpotential, a large capacity, and a good cyclability. |
Persistent Identifier | http://hdl.handle.net/10722/346881 |
ISSN | 2023 Impact Factor: 24.4 2023 SCImago Journal Rankings: 8.748 |
DC Field | Value | Language |
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dc.contributor.author | Lin, Xiaodong | - |
dc.contributor.author | Sun, Zongqiang | - |
dc.contributor.author | Tang, Chun | - |
dc.contributor.author | Hong, Yuhao | - |
dc.contributor.author | Xu, Pan | - |
dc.contributor.author | Cui, Xueyang | - |
dc.contributor.author | Yuan, Ruming | - |
dc.contributor.author | Zhou, Zhiyou | - |
dc.contributor.author | Zheng, Mingsen | - |
dc.contributor.author | Dong, Quanfeng | - |
dc.date.accessioned | 2024-09-17T04:13:54Z | - |
dc.date.available | 2024-09-17T04:13:54Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Advanced Energy Materials, 2020, v. 10, n. 38, article no. 2001592 | - |
dc.identifier.issn | 1614-6832 | - |
dc.identifier.uri | http://hdl.handle.net/10722/346881 | - |
dc.description.abstract | The reduction of O2 to solid Li2O2 on discharge and the reverse oxidation of Li2O2 to O2 on recharge are the essential processes to determine the performance of Li-O2 batteries. The discovery of effective catalysts with a favorable Li2O2 formation/decomposition mechanism is vital for the development of high-performance Li-O2 batteries. Here, a soluble catalyst of iodosylbenzene (PhIO) that can offer a highly reversible O2 conversion is reported for the first time. Benefiting from its ability to capture and couple the LiO2 intermediate, which is endowed by its polarized I3+=O2− bond where the I atom and O atom can serve as a Lewis acidic site and basic site (dual site) to interact with O2− and Li+, respectively, the formation and decomposition of Li2O2 by a one-electron pathway can be effectively promoted, thus greatly improving the electrode surface passivation issue and the reaction kinetics. In addition, the side reactions caused by the traditional high-reactive LiO2 intermediate can also be effectively suppressed by forming a series of low-reactive intermediates (LiO2-3PhIO, (LiO2)2-4PhIO, and Li2O2-4PhIO) instead. Consequently, the PhIO-catalyzed Li–O2 batteries exhibit a low overpotential, a large capacity, and a good cyclability. | - |
dc.language | eng | - |
dc.relation.ispartof | Advanced Energy Materials | - |
dc.subject | iodosylbenzene | - |
dc.subject | Li-O batteries 2 | - |
dc.subject | LiO intermediates 2 | - |
dc.subject | soluble catalysts | - |
dc.title | Highly Reversible O<inf>2</inf> Conversions by Coupling LiO<inf>2</inf> Intermediate through a Dual-Site Catalyst in Li-O<inf>2</inf> Batteries | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/aenm.202001592 | - |
dc.identifier.scopus | eid_2-s2.0-85089368075 | - |
dc.identifier.volume | 10 | - |
dc.identifier.issue | 38 | - |
dc.identifier.spage | article no. 2001592 | - |
dc.identifier.epage | article no. 2001592 | - |
dc.identifier.eissn | 1614-6840 | - |