Development of novel superconductivity with higher Tc via the suppression of magnetism in quasi-two-dimensional electride Y2C under high pressures

Abstract

<p>Discovery of superconductivity in electride materials has been a topic of interest as their intrinsic electron-rich properties might suggest a considerable electron–phonon interaction. Layered Y2C is a ferromagnetic quasi-two-dimensional electride with polarized anionic electrons confined in the interlayer space. In this theoretical study, we report Y2C undergoes a series of structural phase transitions into two superconducting phases with estimated �c of 9.2 and 21.0 K at 19 and 80 GPa, respectively, via the suppression of magnetism. Our extensive first-principles swarm structure searches identify that these two high-pressure superconducting phases possess an orthorhombic <em>Pnma</em> and a tetragonal <em>I</em>4<em>/m</em> structures, respectively, where the <em>Pnma</em> phase is found to be a one-dimensional electride characterized by electron confinements in channel spaces of the crystal lattice, while the electride property in <em>I</em>4<em>/m</em> phase has been completely destroyed. We attribute the development of an unprecedentedly high �c superconductivity in Y-C system to the destructions of magnetism and the delocalization of interlayered anionic electrons under pressures. This work provides a unique example of pressure-induced collapse of magnetism at the onset of superconductivity in electride materials, along with the dramatic changes of electron-confinement topology in crystal lattices.<br></p>