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Article: Enantiopure C5 Pentaindenocorannulenes: Chiral Graphenoid Materials

TitleEnantiopure C<inf>5</inf> Pentaindenocorannulenes: Chiral Graphenoid Materials
Authors
Keywordsabsolute configuration
buckybowls
chirality
pentaindenocorannulene
Issue Date2021
Citation
Angewandte Chemie - International Edition, 2021, v. 60, n. 49, p. 25809-25814 How to Cite?
AbstractChiral carbon nanomaterials offer numerous prospects for material science. As a fundamental building block for non-planar graphenoid materials, pentaindenocorannulene (PIC) with its C5v symmetrical structure presents a platform for creation of supramolecular chiral carbon materials. Specifically, when uniformly penta-substituted on its periphery, PIC generates C5 symmetrical chiral buckybowls capable of columnar stacking. The synthesis and resolution of such PICs are achieved, assignment of absolute configuration is established by comparison of ECD and VCD spectra with theory, and material characterization is reported. Evidence for columnar stacking in solution and in the crystal is presented.
Persistent Identifierhttp://hdl.handle.net/10722/341507
ISSN
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorGuo, Tianjian-
dc.contributor.authorLi, Ansu-
dc.contributor.authorXu, Jun-
dc.contributor.authorBaldridge, Kim K.-
dc.contributor.authorSiegel, Jay-
dc.date.accessioned2024-03-13T08:43:20Z-
dc.date.available2024-03-13T08:43:20Z-
dc.date.issued2021-
dc.identifier.citationAngewandte Chemie - International Edition, 2021, v. 60, n. 49, p. 25809-25814-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/341507-
dc.description.abstractChiral carbon nanomaterials offer numerous prospects for material science. As a fundamental building block for non-planar graphenoid materials, pentaindenocorannulene (PIC) with its C5v symmetrical structure presents a platform for creation of supramolecular chiral carbon materials. Specifically, when uniformly penta-substituted on its periphery, PIC generates C5 symmetrical chiral buckybowls capable of columnar stacking. The synthesis and resolution of such PICs are achieved, assignment of absolute configuration is established by comparison of ECD and VCD spectra with theory, and material characterization is reported. Evidence for columnar stacking in solution and in the crystal is presented.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectabsolute configuration-
dc.subjectbuckybowls-
dc.subjectchirality-
dc.subjectpentaindenocorannulene-
dc.titleEnantiopure C<inf>5</inf> Pentaindenocorannulenes: Chiral Graphenoid Materials-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.202109946-
dc.identifier.pmid34486802-
dc.identifier.scopuseid_2-s2.0-85116005102-
dc.identifier.volume60-
dc.identifier.issue49-
dc.identifier.spage25809-
dc.identifier.epage25814-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:000701793900001-

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