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Conference Paper: Enantioselective synthesis of metal helicates

TitleEnantioselective synthesis of metal helicates
Authors
Woods, Craig R.Benaglia, MaurizioBlom, PetraFuchicello, AugustoCozzi, FrancoSiegel, Jay S.
Issue Date1996
Citation
American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 1996, v. 37, n. 2, p. 480-481 How to Cite?
AbstractThe synthesis and metal complexing behavior of a series of oligobipyridines hybridized to chiral organic templates were investigated to study the possibility of preparing and analyzing specific stereoisomers of the parent helicate in a non-equilibrium mixture. The nuclear magnetic resonance (NMR) spectra of the strand/template hybrids clearly displayed regions of each of the respective protons and carbon types. The methylene region of the free ligands appeared primarily as a set of singlets, due to the accidental isochrony of the diastereotopic protons.
Persistent Identifierhttp://hdl.handle.net/10722/341456
ISSN
0032-3934

 

DC FieldValueLanguage
dc.contributor.authorWoods, Craig R.-
dc.contributor.authorBenaglia, Maurizio-
dc.contributor.authorBlom, Petra-
dc.contributor.authorFuchicello, Augusto-
dc.contributor.authorCozzi, Franco-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:42:57Z-
dc.date.available2024-03-13T08:42:57Z-
dc.date.issued1996-
dc.identifier.citationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 1996, v. 37, n. 2, p. 480-481-
dc.identifier.issn0032-3934-
dc.identifier.urihttp://hdl.handle.net/10722/341456-
dc.description.abstractThe synthesis and metal complexing behavior of a series of oligobipyridines hybridized to chiral organic templates were investigated to study the possibility of preparing and analyzing specific stereoisomers of the parent helicate in a non-equilibrium mixture. The nuclear magnetic resonance (NMR) spectra of the strand/template hybrids clearly displayed regions of each of the respective protons and carbon types. The methylene region of the free ligands appeared primarily as a set of singlets, due to the accidental isochrony of the diastereotopic protons.-
dc.languageeng-
dc.relation.ispartofAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry-
dc.titleEnantioselective synthesis of metal helicates-
dc.typeConference_Paper-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0030204358-
dc.identifier.volume37-
dc.identifier.issue2-
dc.identifier.spage480-
dc.identifier.epage481-

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