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Article: Experimental Observation of the Barrier to Rotation around the Metal-Arene Bond in [1,4-Bis(4,4-dimethyl-3-oxopentyl)-2,3,5,6-tetraethylbenzene]molybdenum Tricarbonyl

TitleExperimental Observation of the Barrier to Rotation around the Metal-Arene Bond in [1,4-Bis(4,4-dimethyl-3-oxopentyl)-2,3,5,6-tetraethylbenzene]molybdenum Tricarbonyl
Authors
Kilway, Kathleen V.Siegel, Jay S.
Issue Date1992
Citation
Organometallics, 1992, v. 11, n. 3, p. 1426-1427 How to Cite?
DOI: http://dx.doi.org/10.1021/om00039a062
AbstractThe barrier to rotation about the metal-arene bond in 1-Mo is deduced from variable-temperature 13C NMR studies. The dynamic stereochemistry of 1-Mo is compared to that of 1-Cr and the free arene 1. Theresults indicate that the tripod rotation barrier is primarily steric in nature. © 1992, American Chemical Society. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/341444
ISSN
0276-7333
2023 Impact Factor: 2.5
2023 SCImago Journal Rankings: 0.654
ISI Accession Number ID
WOS:A1992HH92700062

 

DC FieldValueLanguage
dc.contributor.authorKilway, Kathleen V.-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:42:52Z-
dc.date.available2024-03-13T08:42:52Z-
dc.date.issued1992-
dc.identifier.citationOrganometallics, 1992, v. 11, n. 3, p. 1426-1427-
dc.identifier.issn0276-7333-
dc.identifier.urihttp://hdl.handle.net/10722/341444-
dc.description.abstractThe barrier to rotation about the metal-arene bond in 1-Mo is deduced from variable-temperature 13C NMR studies. The dynamic stereochemistry of 1-Mo is compared to that of 1-Cr and the free arene 1. Theresults indicate that the tripod rotation barrier is primarily steric in nature. © 1992, American Chemical Society. All rights reserved.-
dc.languageeng-
dc.relation.ispartofOrganometallics-
dc.titleExperimental Observation of the Barrier to Rotation around the Metal-Arene Bond in [1,4-Bis(4,4-dimethyl-3-oxopentyl)-2,3,5,6-tetraethylbenzene]molybdenum Tricarbonyl-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/om00039a062-
dc.identifier.scopuseid_2-s2.0-0001607925-
dc.identifier.volume11-
dc.identifier.issue3-
dc.identifier.spage1426-
dc.identifier.epage1427-
dc.identifier.eissn1520-6041-
dc.identifier.isiWOS:A1992HH92700062-

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