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Article: Linear bilateral extended 2,2′:6′,2′′-terpyridine ligands, their coordination complexes and heterometallic supramolecular networks

TitleLinear bilateral extended 2,2′:6′,2′′-terpyridine ligands, their coordination complexes and heterometallic supramolecular networks
Authors
Issue Date2014
Citation
Chemical Science, 2014, v. 5, n. 11, p. 4317-4327 How to Cite?
AbstractOctahedral metal complexes of tridentate 2,2′:6′,2′′-terpyridine (terpy) fused with five-membered furan rings mimic the topology of tetrahedral metal complexes of bidentate 5,5′-functionalized 2,2′-bipyridine (bipy). Herein, we report the robust synthesis of 2,6-bis(2-substituted-furo[2,3-c]pyridine-5-yl)pyridine based ligands to access a series of linear bilateral extended terpy derivatives. This molecular design of alternating five- and six-membered rings has been applied to extend the applicability of terpy as a building block in supramolecular chemistry. The complexation of 2,6-bis(2-substituted-furo[2,3-c]pyridine-5-yl)pyridine derivatives with metal ions preferring octahedral geometry (Fe2+, Ru2+, and Zn2+) gives molecular "crossings" and "corners". Such design elements, functionalized with 4-pyridyl groups, allowed the construction of 3D and 2D heterometallic supramolecular networks containing Fe2+, Ag+or Fe2+, Cu+metal centers.
Persistent Identifierhttp://hdl.handle.net/10722/341155
ISSN
2023 Impact Factor: 7.6
2023 SCImago Journal Rankings: 2.333
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorVeliks, Janis-
dc.contributor.authorTseng, Jui Chang-
dc.contributor.authorArias, Karla I.-
dc.contributor.authorWeisshar, Florian-
dc.contributor.authorLinden, Anthony-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:40:36Z-
dc.date.available2024-03-13T08:40:36Z-
dc.date.issued2014-
dc.identifier.citationChemical Science, 2014, v. 5, n. 11, p. 4317-4327-
dc.identifier.issn2041-6520-
dc.identifier.urihttp://hdl.handle.net/10722/341155-
dc.description.abstractOctahedral metal complexes of tridentate 2,2′:6′,2′′-terpyridine (terpy) fused with five-membered furan rings mimic the topology of tetrahedral metal complexes of bidentate 5,5′-functionalized 2,2′-bipyridine (bipy). Herein, we report the robust synthesis of 2,6-bis(2-substituted-furo[2,3-c]pyridine-5-yl)pyridine based ligands to access a series of linear bilateral extended terpy derivatives. This molecular design of alternating five- and six-membered rings has been applied to extend the applicability of terpy as a building block in supramolecular chemistry. The complexation of 2,6-bis(2-substituted-furo[2,3-c]pyridine-5-yl)pyridine derivatives with metal ions preferring octahedral geometry (Fe2+, Ru2+, and Zn2+) gives molecular "crossings" and "corners". Such design elements, functionalized with 4-pyridyl groups, allowed the construction of 3D and 2D heterometallic supramolecular networks containing Fe2+, Ag+or Fe2+, Cu+metal centers.-
dc.languageeng-
dc.relation.ispartofChemical Science-
dc.titleLinear bilateral extended 2,2′:6′,2′′-terpyridine ligands, their coordination complexes and heterometallic supramolecular networks-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c4sc01025f-
dc.identifier.scopuseid_2-s2.0-84907494750-
dc.identifier.volume5-
dc.identifier.issue11-
dc.identifier.spage4317-
dc.identifier.epage4327-
dc.identifier.eissn2041-6539-
dc.identifier.isiWOS:000343004300026-

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