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Article: Basicity of (2,6-pyridino)paracyclophanes: Lone pair-π, cation-π, and solvation effects

TitleBasicity of (2,6-pyridino)paracyclophanes: Lone pair-π, cation-π, and solvation effects
Authors
Baldridge, Kim K.Cozzi, FrancoSiegel, Jay S.
Keywordsπ interactions
basicity
cations
cyclophanes
solvent effects
Issue Date2012
Citation
Angewandte Chemie - International Edition, 2012, v. 51, n. 12, p. 2903-2906 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.201108545
AbstractLost in solvation: A study of the basicity of (2,6-pyridino)paracyclophanes (see picture; C light blue, N blue, S orange, F yellow, H green) reveals the importance of bulk solvation compared to cation-π effects in determining the relative stability of cations. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/341122
ISSN
1433-7851
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID
WOS:000301430700017

 

DC FieldValueLanguage
dc.contributor.authorBaldridge, Kim K.-
dc.contributor.authorCozzi, Franco-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:40:20Z-
dc.date.available2024-03-13T08:40:20Z-
dc.date.issued2012-
dc.identifier.citationAngewandte Chemie - International Edition, 2012, v. 51, n. 12, p. 2903-2906-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/341122-
dc.description.abstractLost in solvation: A study of the basicity of (2,6-pyridino)paracyclophanes (see picture; C light blue, N blue, S orange, F yellow, H green) reveals the importance of bulk solvation compared to cation-π effects in determining the relative stability of cations. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectπ interactions-
dc.subjectbasicity-
dc.subjectcations-
dc.subjectcyclophanes-
dc.subjectsolvent effects-
dc.titleBasicity of (2,6-pyridino)paracyclophanes: Lone pair-π, cation-π, and solvation effects-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201108545-
dc.identifier.scopuseid_2-s2.0-84858260632-
dc.identifier.volume51-
dc.identifier.issue12-
dc.identifier.spage2903-
dc.identifier.epage2906-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:000301430700017-

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