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Article: Poly(methylhydrosiloxane)-supported chiral imidazolinones: New versatile, highly efficient and recyclable organocatalysts for stereoselective Diels-Alder cycloaddition reactions

TitlePoly(methylhydrosiloxane)-supported chiral imidazolinones: New versatile, highly efficient and recyclable organocatalysts for stereoselective Diels-Alder cycloaddition reactions
Authors
Guizzetti, StefaniaBenaglia, MaurizioSiegel, Jay S.
Issue Date2012
Citation
Chemical Communications, 2012, v. 48, n. 26, p. 3188-3190 How to Cite?
DOI: http://dx.doi.org/10.1039/c2cc17919a
AbstractPoly(methylhydrosiloxane) (PMHS) supported organic catalysts promoted the Diels-Alder reaction of dienes with α,β-unsaturated aldehydes, also in pure water, in yields and enantiomeric excesses comparable to those observed with the non-supported catalysts (up to 93% ee). Recycling of the catalysts was performed with no loss of enantioselectivity for at least five reaction cycles. © 2012 Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/341121
ISSN
1359-7345
2023 Impact Factor: 4.3
2023 SCImago Journal Rankings: 1.133
ISI Accession Number ID
WOS:000300874700012

 

DC FieldValueLanguage
dc.contributor.authorGuizzetti, Stefania-
dc.contributor.authorBenaglia, Maurizio-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:40:19Z-
dc.date.available2024-03-13T08:40:19Z-
dc.date.issued2012-
dc.identifier.citationChemical Communications, 2012, v. 48, n. 26, p. 3188-3190-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/341121-
dc.description.abstractPoly(methylhydrosiloxane) (PMHS) supported organic catalysts promoted the Diels-Alder reaction of dienes with α,β-unsaturated aldehydes, also in pure water, in yields and enantiomeric excesses comparable to those observed with the non-supported catalysts (up to 93% ee). Recycling of the catalysts was performed with no loss of enantioselectivity for at least five reaction cycles. © 2012 Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofChemical Communications-
dc.titlePoly(methylhydrosiloxane)-supported chiral imidazolinones: New versatile, highly efficient and recyclable organocatalysts for stereoselective Diels-Alder cycloaddition reactions-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c2cc17919a-
dc.identifier.pmid22353883-
dc.identifier.scopuseid_2-s2.0-84857706241-
dc.identifier.volume48-
dc.identifier.issue26-
dc.identifier.spage3188-
dc.identifier.epage3190-
dc.identifier.eissn1364-548X-
dc.identifier.isiWOS:000300874700012-

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