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- Publisher Website: 10.1002/anie.201003762
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Article: C-F activation of fluorobenzene by silylium carboranes: Evidence for incipient phenyl cation reactivity
| Title | C-F activation of fluorobenzene by silylium carboranes: Evidence for incipient phenyl cation reactivity |
|---|---|
| Authors | |
| Keywords | C-F activation Carboranes Fluorides Fluorobenzene Silyl cations |
| Issue Date | 2010 |
| Citation | Angewandte Chemie - International Edition, 2010, v. 49, n. 41, p. 7519-7522 How to Cite? |
| Abstract | Si(mply) rips it apart: C-F activation of fluorobenzene has been achieved using the extremely strong silyl Lewis acids [Et3Si(X)]+ (X=PhF or Et3SiH) and [(2,6-dixylyl-C6H 3)SiMe2] + paired with the anion CHB 11Cl11-. They abstract fluoride from unactivated fluorobenzene to give arylated products, consistent with phenyl-cation-like reactivity (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA. |
| Persistent Identifier | http://hdl.handle.net/10722/341114 |
| ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Duttwyler, Simon | - |
| dc.contributor.author | Douvris, Christos | - |
| dc.contributor.author | Fackler, Nathanael L.P. | - |
| dc.contributor.author | Tham, Fook S. | - |
| dc.contributor.author | Reed, Christopher A. | - |
| dc.contributor.author | Baldridge, Kim K. | - |
| dc.contributor.author | Siegel, Jay S. | - |
| dc.date.accessioned | 2024-03-13T08:40:16Z | - |
| dc.date.available | 2024-03-13T08:40:16Z | - |
| dc.date.issued | 2010 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2010, v. 49, n. 41, p. 7519-7522 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/341114 | - |
| dc.description.abstract | Si(mply) rips it apart: C-F activation of fluorobenzene has been achieved using the extremely strong silyl Lewis acids [Et3Si(X)]+ (X=PhF or Et3SiH) and [(2,6-dixylyl-C6H 3)SiMe2] + paired with the anion CHB 11Cl11-. They abstract fluoride from unactivated fluorobenzene to give arylated products, consistent with phenyl-cation-like reactivity (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | C-F activation | - |
| dc.subject | Carboranes | - |
| dc.subject | Fluorides | - |
| dc.subject | Fluorobenzene | - |
| dc.subject | Silyl cations | - |
| dc.title | C-F activation of fluorobenzene by silylium carboranes: Evidence for incipient phenyl cation reactivity | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.201003762 | - |
| dc.identifier.scopus | eid_2-s2.0-77957601704 | - |
| dc.identifier.volume | 49 | - |
| dc.identifier.issue | 41 | - |
| dc.identifier.spage | 7519 | - |
| dc.identifier.epage | 7522 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:000283391800025 | - |