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- Publisher Website: 10.1002/anie.200804563
- Scopus: eid_2-s2.0-61849099303
- WOS: WOS:000264301500015
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Article: Reversible phase transitions in a buckybowl monolayer
| Title | Reversible phase transitions in a buckybowl monolayer |
|---|---|
| Authors | |
| Keywords | Corannulene Phase transitions Polymorphism Scanning probe microscopy Self-assembled monolayers |
| Issue Date | 2009 |
| Citation | Angewandte Chemie - International Edition, 2009, v. 48, n. 11, p. 1966-1969 How to Cite? |
| Abstract | Like penguins on ice, buckybowl molecules move closer together when cooled on a copper surface (see model of a corannulene molecule adsorbed on Cu(111)). Upon heating, the molecules spread out into the original crystal phase again. The lower density at room temperature can be explained by the increase in entropy owing to the excitation of bowl vibrations at the surface. (Figure Presented) © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. |
| Persistent Identifier | http://hdl.handle.net/10722/341108 |
| ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Merz, Leo | - |
| dc.contributor.author | Parschau, Manfred | - |
| dc.contributor.author | Zoppi, Laura | - |
| dc.contributor.author | Baldridge, Kim K. | - |
| dc.contributor.author | Siegel, Jay S. | - |
| dc.contributor.author | Ernst, Karl Heinz | - |
| dc.date.accessioned | 2024-03-13T08:40:13Z | - |
| dc.date.available | 2024-03-13T08:40:13Z | - |
| dc.date.issued | 2009 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2009, v. 48, n. 11, p. 1966-1969 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/341108 | - |
| dc.description.abstract | Like penguins on ice, buckybowl molecules move closer together when cooled on a copper surface (see model of a corannulene molecule adsorbed on Cu(111)). Upon heating, the molecules spread out into the original crystal phase again. The lower density at room temperature can be explained by the increase in entropy owing to the excitation of bowl vibrations at the surface. (Figure Presented) © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | Corannulene | - |
| dc.subject | Phase transitions | - |
| dc.subject | Polymorphism | - |
| dc.subject | Scanning probe microscopy | - |
| dc.subject | Self-assembled monolayers | - |
| dc.title | Reversible phase transitions in a buckybowl monolayer | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.200804563 | - |
| dc.identifier.scopus | eid_2-s2.0-61849099303 | - |
| dc.identifier.volume | 48 | - |
| dc.identifier.issue | 11 | - |
| dc.identifier.spage | 1966 | - |
| dc.identifier.epage | 1969 | - |
| dc.identifier.isi | WOS:000264301500015 | - |