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Article: Synthesis of 2,6-diarylphenyldimethylsilyl cations: Polar-π distribution of cation character

TitleSynthesis of 2,6-diarylphenyldimethylsilyl cations: Polar-π distribution of cation character
Authors
Duttwyler, SimonDo, Quyen QuyenLinden, AnthonyBaldridge, Kim K.Siegel, Jay S.
KeywordsAromatic chemistry
Lewis acids
Polar-π effects
Silicon cations
Stereochemistry
Issue Date2008
Citation
Angewandte Chemie - International Edition, 2008, v. 47, n. 9, p. 1719-1722 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.200705291
AbstractCationic Lewis acidic silicon species constitute a class of reactive intermediates that when "bottled" serve as useful synthetic reagents. A general way to tune the steric environment and Lewis acidic character in such species is presented. (Chemical Equation Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
Persistent Identifierhttp://hdl.handle.net/10722/341107
ISSN
1433-7851
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID
WOS:000253434300026

 

DC FieldValueLanguage
dc.contributor.authorDuttwyler, Simon-
dc.contributor.authorDo, Quyen Quyen-
dc.contributor.authorLinden, Anthony-
dc.contributor.authorBaldridge, Kim K.-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:40:12Z-
dc.date.available2024-03-13T08:40:12Z-
dc.date.issued2008-
dc.identifier.citationAngewandte Chemie - International Edition, 2008, v. 47, n. 9, p. 1719-1722-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/341107-
dc.description.abstractCationic Lewis acidic silicon species constitute a class of reactive intermediates that when "bottled" serve as useful synthetic reagents. A general way to tune the steric environment and Lewis acidic character in such species is presented. (Chemical Equation Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectAromatic chemistry-
dc.subjectLewis acids-
dc.subjectPolar-π effects-
dc.subjectSilicon cations-
dc.subjectStereochemistry-
dc.titleSynthesis of 2,6-diarylphenyldimethylsilyl cations: Polar-π distribution of cation character-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.200705291-
dc.identifier.scopuseid_2-s2.0-53549091860-
dc.identifier.volume47-
dc.identifier.issue9-
dc.identifier.spage1719-
dc.identifier.epage1722-
dc.identifier.isiWOS:000253434300026-

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