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- Publisher Website: 10.1002/anie.199514541
- Scopus: eid_2-s2.0-33748224437
- WOS: WOS:A1995RN12700015
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Article: X‐Ray Diffraction Evidence for a Cyclohexatriene Motif in the Molecular Structure of Tris(bicyclo[2.1.1]hexeno)benzene: Bond Alternation after the Refutation of the Mills–Nixon Theory
| Title | X‐Ray Diffraction Evidence for a Cyclohexatriene Motif in the Molecular Structure of Tris(bicyclo[2.1.1]hexeno)benzene: Bond Alternation after the Refutation of the Mills–Nixon Theory |
|---|---|
| Authors | |
| Keywords | bond length alternation cyclohexatriene Mills–Nixon effect |
| Issue Date | 1995 |
| Citation | Angewandte Chemie International Edition in English, 1995, v. 34, n. 13-14, p. 1454-1456 How to Cite? |
| Abstract | Cyclohexatriene lost, cyclohexatriene regained! Recently the Mills–Nixon postulate concerning the structure of benzene derivatives was recognized to be invalid. A new view on strain‐induced bond localization in benzene led to the design and synthesis of tris(bicyclo[2.1.1]hexeno)benzene (1), which shows significant distortion toward a cyclohexatriene geometry. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany |
| Persistent Identifier | http://hdl.handle.net/10722/341091 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Bürgi, Hans‐Beat ‐B | - |
| dc.contributor.author | Baldridge, Kim K. | - |
| dc.contributor.author | Hardcastle, Kenneth | - |
| dc.contributor.author | Frank, Natia L. | - |
| dc.contributor.author | Gantzel, Peter | - |
| dc.contributor.author | Siegel, Jay S. | - |
| dc.contributor.author | Ziller, Joseph | - |
| dc.date.accessioned | 2024-03-13T08:40:04Z | - |
| dc.date.available | 2024-03-13T08:40:04Z | - |
| dc.date.issued | 1995 | - |
| dc.identifier.citation | Angewandte Chemie International Edition in English, 1995, v. 34, n. 13-14, p. 1454-1456 | - |
| dc.identifier.issn | 0570-0833 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/341091 | - |
| dc.description.abstract | Cyclohexatriene lost, cyclohexatriene regained! Recently the Mills–Nixon postulate concerning the structure of benzene derivatives was recognized to be invalid. A new view on strain‐induced bond localization in benzene led to the design and synthesis of tris(bicyclo[2.1.1]hexeno)benzene (1), which shows significant distortion toward a cyclohexatriene geometry. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie International Edition in English | - |
| dc.subject | bond length alternation | - |
| dc.subject | cyclohexatriene | - |
| dc.subject | Mills–Nixon effect | - |
| dc.title | X‐Ray Diffraction Evidence for a Cyclohexatriene Motif in the Molecular Structure of Tris(bicyclo[2.1.1]hexeno)benzene: Bond Alternation after the Refutation of the Mills–Nixon Theory | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.199514541 | - |
| dc.identifier.scopus | eid_2-s2.0-33748224437 | - |
| dc.identifier.volume | 34 | - |
| dc.identifier.issue | 13-14 | - |
| dc.identifier.spage | 1454 | - |
| dc.identifier.epage | 1456 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:A1995RN12700015 | - |