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Article: Polar Interactions between Stacked π Systems in Fluorinated 1,8‐Diarylnaphthalenes: Importance of Quadrupole Moments in Molecular Recognition

TitlePolar Interactions between Stacked π Systems in Fluorinated 1,8‐Diarylnaphthalenes: Importance of Quadrupole Moments in Molecular Recognition
Authors
Cozzi, FrancoPonzini, FrancescoAnnunziata, RitaCinquini, MauroSiegel, Jay S.
Keywordsfluorine compounds
molecular recognition
stacking interactions
Issue Date1995
Citation
Angewandte Chemie International Edition in English, 1995, v. 34, n. 9, p. 1019-1020 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.199510191
AbstractT‐shaped arrangements in the homodimers A and C of benzene and hexafluorobenzene, respectively, are rationalized by polar effects, but face‐to‐face stacking dominates in the 1:1 heterodimer B. The dynamics of a series of fluorinated 1,8‐diarylnaphthalenes clearly demonstrate the dependence of arene–arene interactions on the electronic characteristics of the arenes. The results are important for the design of supramolecular structures. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
Persistent Identifierhttp://hdl.handle.net/10722/341088
ISSN
0570-0833
ISI Accession Number ID
WOS:A1995RB00200019

 

DC FieldValueLanguage
dc.contributor.authorCozzi, Franco-
dc.contributor.authorPonzini, Francesco-
dc.contributor.authorAnnunziata, Rita-
dc.contributor.authorCinquini, Mauro-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:40:03Z-
dc.date.available2024-03-13T08:40:03Z-
dc.date.issued1995-
dc.identifier.citationAngewandte Chemie International Edition in English, 1995, v. 34, n. 9, p. 1019-1020-
dc.identifier.issn0570-0833-
dc.identifier.urihttp://hdl.handle.net/10722/341088-
dc.description.abstractT‐shaped arrangements in the homodimers A and C of benzene and hexafluorobenzene, respectively, are rationalized by polar effects, but face‐to‐face stacking dominates in the 1:1 heterodimer B. The dynamics of a series of fluorinated 1,8‐diarylnaphthalenes clearly demonstrate the dependence of arene–arene interactions on the electronic characteristics of the arenes. The results are important for the design of supramolecular structures. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie International Edition in English-
dc.subjectfluorine compounds-
dc.subjectmolecular recognition-
dc.subjectstacking interactions-
dc.titlePolar Interactions between Stacked π Systems in Fluorinated 1,8‐Diarylnaphthalenes: Importance of Quadrupole Moments in Molecular Recognition-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.199510191-
dc.identifier.scopuseid_2-s2.0-33748212084-
dc.identifier.volume34-
dc.identifier.issue9-
dc.identifier.spage1019-
dc.identifier.epage1020-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:A1995RB00200019-

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