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Article: Synthesis and properties of sym-pentasubstituted derivatives of corannulene

TitleSynthesis and properties of sym-pentasubstituted derivatives of corannulene
Authors
Grube, Gunther H.Elliott, Eric L.Steffens, Ralph J.Jones, Carissa S.Baldridge, Kim K.Siegel, Jay S.
Issue Date2003
Citation
Organic Letters, 2003, v. 5, n. 5, p. 713-716 How to Cite?
DOI: http://dx.doi.org/10.1021/ol027565f
Abstract(Figure presented) Alkyl, aryl, and alkynyl as well as heteroatom derivatives of sym-pentasubstituted corannulenes have been synthesized from syrn-pentachlorocorannulene. These units form potential building blocks for future work on superstructures based on corannulene. Absorption/emission properties follow expected trends from the parent 1. sym-Pentasubstitution gives rise to variations in the chemical dynamics of bowl inversion, van der Waals attraction is cited to explain an anomalously high barrier to bowl inversion in 10.
Persistent Identifierhttp://hdl.handle.net/10722/341064
ISSN
1523-7060
2023 Impact Factor: 4.9
2023 SCImago Journal Rankings: 1.245
ISI Accession Number ID
WOS:000181233000028

 

DC FieldValueLanguage
dc.contributor.authorGrube, Gunther H.-
dc.contributor.authorElliott, Eric L.-
dc.contributor.authorSteffens, Ralph J.-
dc.contributor.authorJones, Carissa S.-
dc.contributor.authorBaldridge, Kim K.-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:39:52Z-
dc.date.available2024-03-13T08:39:52Z-
dc.date.issued2003-
dc.identifier.citationOrganic Letters, 2003, v. 5, n. 5, p. 713-716-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/341064-
dc.description.abstract(Figure presented) Alkyl, aryl, and alkynyl as well as heteroatom derivatives of sym-pentasubstituted corannulenes have been synthesized from syrn-pentachlorocorannulene. These units form potential building blocks for future work on superstructures based on corannulene. Absorption/emission properties follow expected trends from the parent 1. sym-Pentasubstitution gives rise to variations in the chemical dynamics of bowl inversion, van der Waals attraction is cited to explain an anomalously high barrier to bowl inversion in 10.-
dc.languageeng-
dc.relation.ispartofOrganic Letters-
dc.titleSynthesis and properties of sym-pentasubstituted derivatives of corannulene-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol027565f-
dc.identifier.pmid12605497-
dc.identifier.scopuseid_2-s2.0-0141746180-
dc.identifier.volume5-
dc.identifier.issue5-
dc.identifier.spage713-
dc.identifier.epage716-
dc.identifier.isiWOS:000181233000028-

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