File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Interaction between stacked aryl groups in 1, 8-diarylnaphthalenes: Dominance of polar/π over charge-transfer effects

TitleInteraction between stacked aryl groups in 1, 8-diarylnaphthalenes: Dominance of polar/π over charge-transfer effects
Authors
Issue Date1995
Citation
Pure and Applied Chemistry, 1995, v. 67, n. 5, p. 683-689 How to Cite?
AbstractSeveral 1, 8-diarylnaphthalenes have been prepared, and the barrier to rotation around the aryl/naphthalene bond has been measured. In these molecules steric congestion forces the aryls in a parallel stacked geometry. The barriers to rotation were used to evaluate the strength and to investigate the nature of the interaction between the arenes. The variance of the AG* for the rotation upon arene substitution with electron donating or electron withdrawing groups indicates that polar/π electrostatic effects dominate over charge-transfer effects in determining the arene/arene interaction. © 1995 IUPAC
Persistent Identifierhttp://hdl.handle.net/10722/341061
ISSN
2023 Impact Factor: 2.0
2023 SCImago Journal Rankings: 0.435
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorSiegel, Jay S.-
dc.contributor.authorCozzi, Franco-
dc.date.accessioned2024-03-13T08:39:50Z-
dc.date.available2024-03-13T08:39:50Z-
dc.date.issued1995-
dc.identifier.citationPure and Applied Chemistry, 1995, v. 67, n. 5, p. 683-689-
dc.identifier.issn0033-4545-
dc.identifier.urihttp://hdl.handle.net/10722/341061-
dc.description.abstractSeveral 1, 8-diarylnaphthalenes have been prepared, and the barrier to rotation around the aryl/naphthalene bond has been measured. In these molecules steric congestion forces the aryls in a parallel stacked geometry. The barriers to rotation were used to evaluate the strength and to investigate the nature of the interaction between the arenes. The variance of the AG* for the rotation upon arene substitution with electron donating or electron withdrawing groups indicates that polar/π electrostatic effects dominate over charge-transfer effects in determining the arene/arene interaction. © 1995 IUPAC-
dc.languageeng-
dc.relation.ispartofPure and Applied Chemistry-
dc.titleInteraction between stacked aryl groups in 1, 8-diarylnaphthalenes: Dominance of polar/π over charge-transfer effects-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1351/pac199567050683-
dc.identifier.scopuseid_2-s2.0-0343417831-
dc.identifier.volume67-
dc.identifier.issue5-
dc.identifier.spage683-
dc.identifier.epage689-
dc.identifier.eissn1365-3075-
dc.identifier.isiWOS:A1995QZ02500004-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats