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Article: Synthesis, Structure, and Dynamics of endo-(Starphenylene)chromium Tricarbonyl Derivatives: Observation of Metal-Arene Migration and Hindered Metal-Tripod Rotation

TitleSynthesis, Structure, and Dynamics of endo-(Starphenylene)chromium Tricarbonyl Derivatives: Observation of Metal-Arene Migration and Hindered Metal-Tripod Rotation
Authors
Nambu, MitchSiegel, Jay S.Mohler, Debra L.Hardcastle, KennethBaldridge, Kim K.
Issue Date1993
Citation
Journal of the American Chemical Society, 1993, v. 115, n. 14, p. 6138-6142 How to Cite?
DOI: http://dx.doi.org/10.1021/ja00067a032
AbstractThe dynamic stereochemistry of endo-(starphenylene)chromium tricarbonyl, endo-1-Cr, is elucidated through NMR spectroscopic methods. Intramolecular metal-arene migration and hindered metal-tripod rotation are observed in closely related derivatives of endo-1-Cr. The stereochemistry of these systems is modeled well by ab initio local density functional theory methods. © 1993, American Chemical Society. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/341030
ISSN
0002-7863
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID
WOS:A1993LT17300032

 

DC FieldValueLanguage
dc.contributor.authorNambu, Mitch-
dc.contributor.authorSiegel, Jay S.-
dc.contributor.authorMohler, Debra L.-
dc.contributor.authorHardcastle, Kenneth-
dc.contributor.authorBaldridge, Kim K.-
dc.date.accessioned2024-03-13T08:39:36Z-
dc.date.available2024-03-13T08:39:36Z-
dc.date.issued1993-
dc.identifier.citationJournal of the American Chemical Society, 1993, v. 115, n. 14, p. 6138-6142-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/341030-
dc.description.abstractThe dynamic stereochemistry of endo-(starphenylene)chromium tricarbonyl, endo-1-Cr, is elucidated through NMR spectroscopic methods. Intramolecular metal-arene migration and hindered metal-tripod rotation are observed in closely related derivatives of endo-1-Cr. The stereochemistry of these systems is modeled well by ab initio local density functional theory methods. © 1993, American Chemical Society. All rights reserved.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleSynthesis, Structure, and Dynamics of endo-(Starphenylene)chromium Tricarbonyl Derivatives: Observation of Metal-Arene Migration and Hindered Metal-Tripod Rotation-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja00067a032-
dc.identifier.scopuseid_2-s2.0-0001622998-
dc.identifier.volume115-
dc.identifier.issue14-
dc.identifier.spage6138-
dc.identifier.epage6142-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:A1993LT17300032-

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