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- Publisher Website: 10.1002/anie.201006877
- Scopus: eid_2-s2.0-78751565048
- PMID: 21246679
- WOS: WOS:000287157600011
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Article: Stereoselective coordination of C5 -symmetric corannulene derivatives with an enantiomerically pure [RhI(nbd*)] metal complex
| Title | Stereoselective coordination of C<inf>5</inf>-symmetric corannulene derivatives with an enantiomerically pure [Rh<sup>I</sup>(nbd*)] metal complex |
|---|---|
| Authors | |
| Keywords | corannulenes dynamic NMR spectroscopy metal-arene complexes stereochemistry |
| Issue Date | 2011 |
| Citation | Angewandte Chemie - International Edition, 2011, v. 50, n. 4, p. 865-867 How to Cite? |
| Abstract | Catching the bowl! Enantiopure RhI dimethylnorbornadiene fragments selectively catch interconverting enantiomers of C5-sym- pentasubstituted corannulene derivatives in one bowl form and allow the observation and isolation of enantiopure metal-buckybowl complexes. A quantum mechanical model (see picture) predicts the mechanism of molecular dynamics and degree of stereoselective recognition. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Persistent Identifier | http://hdl.handle.net/10722/341013 |
| ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Bandera, Davide | - |
| dc.contributor.author | Baldridge, Kim K. | - |
| dc.contributor.author | Linden, Anthony | - |
| dc.contributor.author | Dorta, Reto | - |
| dc.contributor.author | Siegel, Jay S. | - |
| dc.date.accessioned | 2024-03-13T08:39:28Z | - |
| dc.date.available | 2024-03-13T08:39:28Z | - |
| dc.date.issued | 2011 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2011, v. 50, n. 4, p. 865-867 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/341013 | - |
| dc.description.abstract | Catching the bowl! Enantiopure RhI dimethylnorbornadiene fragments selectively catch interconverting enantiomers of C5-sym- pentasubstituted corannulene derivatives in one bowl form and allow the observation and isolation of enantiopure metal-buckybowl complexes. A quantum mechanical model (see picture) predicts the mechanism of molecular dynamics and degree of stereoselective recognition. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | corannulenes | - |
| dc.subject | dynamic NMR spectroscopy | - |
| dc.subject | metal-arene complexes | - |
| dc.subject | stereochemistry | - |
| dc.title | Stereoselective coordination of C<inf>5</inf>-symmetric corannulene derivatives with an enantiomerically pure [Rh<sup>I</sup>(nbd*)] metal complex | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.201006877 | - |
| dc.identifier.pmid | 21246679 | - |
| dc.identifier.scopus | eid_2-s2.0-78751565048 | - |
| dc.identifier.volume | 50 | - |
| dc.identifier.issue | 4 | - |
| dc.identifier.spage | 865 | - |
| dc.identifier.epage | 867 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:000287157600011 | - |