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Article: Stereoselective coordination of C5-symmetric corannulene derivatives with an enantiomerically pure [RhI(nbd*)] metal complex

TitleStereoselective coordination of C<inf>5</inf>-symmetric corannulene derivatives with an enantiomerically pure [Rh<sup>I</sup>(nbd*)] metal complex
Authors
Keywordscorannulenes
dynamic NMR spectroscopy
metal-arene complexes
stereochemistry
Issue Date2011
Citation
Angewandte Chemie - International Edition, 2011, v. 50, n. 4, p. 865-867 How to Cite?
AbstractCatching the bowl! Enantiopure RhI dimethylnorbornadiene fragments selectively catch interconverting enantiomers of C5-sym- pentasubstituted corannulene derivatives in one bowl form and allow the observation and isolation of enantiopure metal-buckybowl complexes. A quantum mechanical model (see picture) predicts the mechanism of molecular dynamics and degree of stereoselective recognition. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/341013
ISSN
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorBandera, Davide-
dc.contributor.authorBaldridge, Kim K.-
dc.contributor.authorLinden, Anthony-
dc.contributor.authorDorta, Reto-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:39:28Z-
dc.date.available2024-03-13T08:39:28Z-
dc.date.issued2011-
dc.identifier.citationAngewandte Chemie - International Edition, 2011, v. 50, n. 4, p. 865-867-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/341013-
dc.description.abstractCatching the bowl! Enantiopure RhI dimethylnorbornadiene fragments selectively catch interconverting enantiomers of C5-sym- pentasubstituted corannulene derivatives in one bowl form and allow the observation and isolation of enantiopure metal-buckybowl complexes. A quantum mechanical model (see picture) predicts the mechanism of molecular dynamics and degree of stereoselective recognition. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectcorannulenes-
dc.subjectdynamic NMR spectroscopy-
dc.subjectmetal-arene complexes-
dc.subjectstereochemistry-
dc.titleStereoselective coordination of C<inf>5</inf>-symmetric corannulene derivatives with an enantiomerically pure [Rh<sup>I</sup>(nbd*)] metal complex-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201006877-
dc.identifier.pmid21246679-
dc.identifier.scopuseid_2-s2.0-78751565048-
dc.identifier.volume50-
dc.identifier.issue4-
dc.identifier.spage865-
dc.identifier.epage867-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:000287157600011-

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