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- Publisher Website: 10.1021/acs.organomet.5b00488
- Scopus: eid_2-s2.0-84940199924
- WOS: WOS:000360322500017
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Article: Facile Aerobic Alkylation of Rhodium Porphyrins with Alkyl Halides
| Title | Facile Aerobic Alkylation of Rhodium Porphyrins with Alkyl Halides |
|---|---|
| Authors | |
| Issue Date | 2015 |
| Citation | Organometallics, 2015, v. 34, n. 16, p. 4051-4057 How to Cite? |
| Abstract | Alkylation of rhodium porphyrins was achieved in moderate to high yields in the presence of air and water. With this facile alkylation method, various alkyl RhIII(por) species, including those with tertiary alkyl, were synthesized. Mechanistic investigations suggest a parallel S |
| Persistent Identifier | http://hdl.handle.net/10722/336143 |
| ISSN | 2023 Impact Factor: 2.5 2023 SCImago Journal Rankings: 0.654 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Yang, Wu | - |
| dc.contributor.author | Zuo, Huiping | - |
| dc.contributor.author | Lai, Wai Yan | - |
| dc.contributor.author | Feng, Shiyu | - |
| dc.contributor.author | Pang, Yat Sing | - |
| dc.contributor.author | Hung, Kai En | - |
| dc.contributor.author | Yu, Chu Yi | - |
| dc.contributor.author | Lau, Yin Fan | - |
| dc.contributor.author | Tsoi, Ho Yin | - |
| dc.contributor.author | Chan, Kin Shing | - |
| dc.date.accessioned | 2024-01-15T08:23:52Z | - |
| dc.date.available | 2024-01-15T08:23:52Z | - |
| dc.date.issued | 2015 | - |
| dc.identifier.citation | Organometallics, 2015, v. 34, n. 16, p. 4051-4057 | - |
| dc.identifier.issn | 0276-7333 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/336143 | - |
| dc.description.abstract | Alkylation of rhodium porphyrins was achieved in moderate to high yields in the presence of air and water. With this facile alkylation method, various alkyl Rh<sup>III</sup>(por) species, including those with tertiary alkyl, were synthesized. Mechanistic investigations suggest a parallel S<inf>N</inf>2 via [Rh<sup>I</sup>(ttp)]<sup>-</sup> with halogen atom transfer pathway via [Rh<sup>II</sup>(ttp)]<sup>•</sup>. (Chemical Equation Presented). | - |
| dc.language | eng | - |
| dc.relation.ispartof | Organometallics | - |
| dc.title | Facile Aerobic Alkylation of Rhodium Porphyrins with Alkyl Halides | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/acs.organomet.5b00488 | - |
| dc.identifier.scopus | eid_2-s2.0-84940199924 | - |
| dc.identifier.volume | 34 | - |
| dc.identifier.issue | 16 | - |
| dc.identifier.spage | 4051 | - |
| dc.identifier.epage | 4057 | - |
| dc.identifier.eissn | 1520-6041 | - |
| dc.identifier.isi | WOS:000360322500017 | - |