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- Publisher Website: 10.1021/jacs.2c05946
- Scopus: eid_2-s2.0-85140829531
- WOS: WOS:000880023700001
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Article: Stimuli-Induced Reversible Transformation between Decanuclear and Pentanuclear Gold(I) Sulfido Complexes
| Title | Stimuli-Induced Reversible Transformation between Decanuclear and Pentanuclear Gold(I) Sulfido Complexes |
|---|---|
| Authors | |
| Issue Date | 20-Oct-2022 |
| Publisher | American Chemical Society |
| Citation | Journal of the American Chemical Society, 2022, v. 144, n. 43, p. 19748-19757 How to Cite? |
| Abstract | Decanuclear and pentanuclear gold(I) sulfido complexes of phenanthrene-and dibenzothiophene-based diphos-phine ligands were synthesized and characterized. Unprecedented stimuli-induced reversible transformation between decanuclear and pentanuclear gold(I) sulfido complexes was observed, which could be readily monitored by NMR and UV-vis absorption spectros-copy in solution. Remarkably, the decanuclear gold(I) sulfido complex (Au10-LPh) was found to show a highly reversible transformation process, which is stable for over 10 successive cycles in solution. The stimuli-induced reversible transformation behavior of the gold(I) sulfido complexes was found to depend on the P-P bite distance of the bidentate phosphine ligands. |
| Persistent Identifier | http://hdl.handle.net/10722/333959 |
| ISSN | 2023 Impact Factor: 14.4 2023 SCImago Journal Rankings: 5.489 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Yan, Liang-Liang | - |
| dc.contributor.author | Yao, Liao-Yuan | - |
| dc.contributor.author | Ng, Maggie | - |
| dc.contributor.author | Tang, Wai Kit | - |
| dc.contributor.author | Leung, Ming-Yi | - |
| dc.contributor.author | Yam, Vivian Wing-Wah | - |
| dc.date.accessioned | 2023-10-10T03:14:56Z | - |
| dc.date.available | 2023-10-10T03:14:56Z | - |
| dc.date.issued | 2022-10-20 | - |
| dc.identifier.citation | Journal of the American Chemical Society, 2022, v. 144, n. 43, p. 19748-19757 | - |
| dc.identifier.issn | 0002-7863 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/333959 | - |
| dc.description.abstract | <p>Decanuclear and pentanuclear gold(I) sulfido complexes of phenanthrene-and dibenzothiophene-based diphos-phine ligands were synthesized and characterized. Unprecedented stimuli-induced reversible transformation between decanuclear and pentanuclear gold(I) sulfido complexes was observed, which could be readily monitored by NMR and UV-vis absorption spectros-copy in solution. Remarkably, the decanuclear gold(I) sulfido complex (Au10-LPh) was found to show a highly reversible transformation process, which is stable for over 10 successive cycles in solution. The stimuli-induced reversible transformation behavior of the gold(I) sulfido complexes was found to depend on the P-P bite distance of the bidentate phosphine ligands.<br></p> | - |
| dc.language | eng | - |
| dc.publisher | American Chemical Society | - |
| dc.relation.ispartof | Journal of the American Chemical Society | - |
| dc.title | Stimuli-Induced Reversible Transformation between Decanuclear and Pentanuclear Gold(I) Sulfido Complexes | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1021/jacs.2c05946 | - |
| dc.identifier.scopus | eid_2-s2.0-85140829531 | - |
| dc.identifier.volume | 144 | - |
| dc.identifier.issue | 43 | - |
| dc.identifier.spage | 19748 | - |
| dc.identifier.epage | 19757 | - |
| dc.identifier.eissn | 1520-5126 | - |
| dc.identifier.isi | WOS:000880023700001 | - |
| dc.identifier.issnl | 0002-7863 | - |