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Article: Metal-organic framework thin films composed of free-standing acicular nanorods exhibiting reversible electrochromism

TitleMetal-organic framework thin films composed of free-standing acicular nanorods exhibiting reversible electrochromism
Authors
Kung, Chung WeiWang, Timothy ChiaanMondloch, Joseph E.Fairen-Jimenez, DavidGardner, Daniel M.Bury, WojciechKlingsporn, Jordan MatthewBarnes, Jonathan C.Van Duyne, RichardStoddart, J. FraserWasielewski, Michael R.Farha, Omar K.Hupp, Joseph T.
Keywordselectrochromism
metal-organic frameworks
one-dimensional nanorods
pyrene
Issue Date2013
Citation
Chemistry of Materials, 2013, v. 25, n. 24, p. 5012-5017 How to Cite?
DOI: http://dx.doi.org/10.1021/cm403726v
AbstractA uniform and crack-free metal-organic framework (MOF) thin film composed of free-standing acicular nanorods was grown on a transparent conducting glass substrate. The MOF thin film exhibits electrochromic switching between yellow and deep blue by means of a one-electron redox reaction at its pyrene-based linkers. The rigid MOF stabilizes the radical cations of the pyrene linkers at positive applied potential, resulting in the reversible color change of the MOF film. The regular and uniform channels of the MOF allow ions to migrate through the entire film. The MOF thin film thus exhibits a remarkable color change and rapid switching rate. © 2013 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/333680
ISSN
0897-4756
2023 Impact Factor: 7.2
2023 SCImago Journal Rankings: 2.421
ISI Accession Number ID
WOS:000329137800021

 

DC FieldValueLanguage
dc.contributor.authorKung, Chung Wei-
dc.contributor.authorWang, Timothy Chiaan-
dc.contributor.authorMondloch, Joseph E.-
dc.contributor.authorFairen-Jimenez, David-
dc.contributor.authorGardner, Daniel M.-
dc.contributor.authorBury, Wojciech-
dc.contributor.authorKlingsporn, Jordan Matthew-
dc.contributor.authorBarnes, Jonathan C.-
dc.contributor.authorVan Duyne, Richard-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWasielewski, Michael R.-
dc.contributor.authorFarha, Omar K.-
dc.contributor.authorHupp, Joseph T.-
dc.date.accessioned2023-10-06T05:21:32Z-
dc.date.available2023-10-06T05:21:32Z-
dc.date.issued2013-
dc.identifier.citationChemistry of Materials, 2013, v. 25, n. 24, p. 5012-5017-
dc.identifier.issn0897-4756-
dc.identifier.urihttp://hdl.handle.net/10722/333680-
dc.description.abstractA uniform and crack-free metal-organic framework (MOF) thin film composed of free-standing acicular nanorods was grown on a transparent conducting glass substrate. The MOF thin film exhibits electrochromic switching between yellow and deep blue by means of a one-electron redox reaction at its pyrene-based linkers. The rigid MOF stabilizes the radical cations of the pyrene linkers at positive applied potential, resulting in the reversible color change of the MOF film. The regular and uniform channels of the MOF allow ions to migrate through the entire film. The MOF thin film thus exhibits a remarkable color change and rapid switching rate. © 2013 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofChemistry of Materials-
dc.subjectelectrochromism-
dc.subjectmetal-organic frameworks-
dc.subjectone-dimensional nanorods-
dc.subjectpyrene-
dc.titleMetal-organic framework thin films composed of free-standing acicular nanorods exhibiting reversible electrochromism-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/cm403726v-
dc.identifier.scopuseid_2-s2.0-84896533106-
dc.identifier.volume25-
dc.identifier.issue24-
dc.identifier.spage5012-
dc.identifier.epage5017-
dc.identifier.eissn1520-5002-
dc.identifier.isiWOS:000329137800021-

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