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Article: A new protocol for rotaxane synthesis

TitleA new protocol for rotaxane synthesis
Authors
Cantrill, Stuart J.Fulton, David A.Fyfe, Matthew C.T.Stoddart, J. FraserWhite, Andrew J.P.Williams, David J.
KeywordsRotaxanes
Self-assembly
Synthetic methods
Template synthesis
Issue Date1999
Citation
Tetrahedron Letters, 1999, v. 40, n. 19, p. 3669-3672 How to Cite?
DOI: http://dx.doi.org/10.1016/S0040-4039(99)00555-9
AbstractA novel [2]rotaxane was synthesized when an aniline-bearing [2]pseudorotaxane-generated by the hydrogen bond-driven threading of a dibenzylammonium filament through the cavity of the macrocyclic polyether dibenzo[24]crown-8-was stoppered via reaction with a bulky isocyanate. Complete characterization of the [2]rotaxane was accomplished by NMR spectroscopy, mass spectrometry and X-ray crystallography.
Persistent Identifierhttp://hdl.handle.net/10722/333589
ISSN
0040-4039
2023 Impact Factor: 1.5
2023 SCImago Journal Rankings: 0.323
ISI Accession Number ID
WOS:000079912700004

 

DC FieldValueLanguage
dc.contributor.authorCantrill, Stuart J.-
dc.contributor.authorFulton, David A.-
dc.contributor.authorFyfe, Matthew C.T.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWhite, Andrew J.P.-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:20:50Z-
dc.date.available2023-10-06T05:20:50Z-
dc.date.issued1999-
dc.identifier.citationTetrahedron Letters, 1999, v. 40, n. 19, p. 3669-3672-
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10722/333589-
dc.description.abstractA novel [2]rotaxane was synthesized when an aniline-bearing [2]pseudorotaxane-generated by the hydrogen bond-driven threading of a dibenzylammonium filament through the cavity of the macrocyclic polyether dibenzo[24]crown-8-was stoppered via reaction with a bulky isocyanate. Complete characterization of the [2]rotaxane was accomplished by NMR spectroscopy, mass spectrometry and X-ray crystallography.-
dc.languageeng-
dc.relation.ispartofTetrahedron Letters-
dc.subjectRotaxanes-
dc.subjectSelf-assembly-
dc.subjectSynthetic methods-
dc.subjectTemplate synthesis-
dc.titleA new protocol for rotaxane synthesis-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0040-4039(99)00555-9-
dc.identifier.scopuseid_2-s2.0-0033532127-
dc.identifier.volume40-
dc.identifier.issue19-
dc.identifier.spage3669-
dc.identifier.epage3672-
dc.identifier.isiWOS:000079912700004-

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