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Article: Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

TitleReticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption
Authors
Issue Date2019
Citation
Journal of the American Chemical Society, 2019, v. 141, n. 7, p. 2900-2905 How to Cite?
AbstractMetal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.
Persistent Identifierhttp://hdl.handle.net/10722/333363
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChen, Zhijie-
dc.contributor.authorLi, Penghao-
dc.contributor.authorZhang, Xuan-
dc.contributor.authorLi, Peng-
dc.contributor.authorWasson, Megan C.-
dc.contributor.authorIslamoglu, Timur-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorFarha, Omar K.-
dc.date.accessioned2023-10-06T05:18:46Z-
dc.date.available2023-10-06T05:18:46Z-
dc.date.issued2019-
dc.identifier.citationJournal of the American Chemical Society, 2019, v. 141, n. 7, p. 2900-2905-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/333363-
dc.description.abstractMetal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleReticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jacs.8b13710-
dc.identifier.pmid30735359-
dc.identifier.scopuseid_2-s2.0-85061537747-
dc.identifier.volume141-
dc.identifier.issue7-
dc.identifier.spage2900-
dc.identifier.epage2905-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000459642000021-

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