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- Publisher Website: 10.1002/chem.201604972
- Scopus: eid_2-s2.0-85006063449
- PMID: 27780293
- WOS: WOS:000393599700032
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Article: Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal–Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard
Title | Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal–Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard |
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Authors | |
Keywords | fullerene metal–organic frameworks pyrene singlet oxygen sulfur mustard |
Issue Date | 2017 |
Citation | Chemistry - A European Journal, 2017, v. 23, n. 1, p. 214-218 How to Cite? |
Abstract | A fullerene-based photosensitizer is incorporated postsynthetically into a Zr6-based MOF, NU-1000, for enhanced singlet oxygen production. The structural organic linkers in the MOF platform also act as photosensitizers which contribute to the overall generation of singlet oxygen from the material under UV irradiation. The singlet oxygen generated by the MOF/fullerene material is shown to oxidize sulfur mustard selectively to the less toxic bis(2-chloroethyl)sulfoxide with a half-life of only 11 min. |
Persistent Identifier | http://hdl.handle.net/10722/333251 |
ISSN | 2023 Impact Factor: 3.9 2023 SCImago Journal Rankings: 1.058 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Howarth, Ashlee J. | - |
dc.contributor.author | Buru, Cassandra T. | - |
dc.contributor.author | Liu, Yangyang | - |
dc.contributor.author | Ploskonka, Ann M. | - |
dc.contributor.author | Hartlieb, Karel J. | - |
dc.contributor.author | McEntee, Monica | - |
dc.contributor.author | Mahle, John J. | - |
dc.contributor.author | Buchanan, James H. | - |
dc.contributor.author | Durke, Erin M. | - |
dc.contributor.author | Al-Juaid, Salih S. | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.contributor.author | DeCoste, Jared B. | - |
dc.contributor.author | Hupp, Joseph T. | - |
dc.contributor.author | Farha, Omar K. | - |
dc.date.accessioned | 2023-10-06T05:17:53Z | - |
dc.date.available | 2023-10-06T05:17:53Z | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | Chemistry - A European Journal, 2017, v. 23, n. 1, p. 214-218 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/10722/333251 | - |
dc.description.abstract | A fullerene-based photosensitizer is incorporated postsynthetically into a Zr6-based MOF, NU-1000, for enhanced singlet oxygen production. The structural organic linkers in the MOF platform also act as photosensitizers which contribute to the overall generation of singlet oxygen from the material under UV irradiation. The singlet oxygen generated by the MOF/fullerene material is shown to oxidize sulfur mustard selectively to the less toxic bis(2-chloroethyl)sulfoxide with a half-life of only 11 min. | - |
dc.language | eng | - |
dc.relation.ispartof | Chemistry - A European Journal | - |
dc.subject | fullerene | - |
dc.subject | metal–organic frameworks | - |
dc.subject | pyrene | - |
dc.subject | singlet oxygen | - |
dc.subject | sulfur mustard | - |
dc.title | Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal–Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/chem.201604972 | - |
dc.identifier.pmid | 27780293 | - |
dc.identifier.scopus | eid_2-s2.0-85006063449 | - |
dc.identifier.volume | 23 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 214 | - |
dc.identifier.epage | 218 | - |
dc.identifier.eissn | 1521-3765 | - |
dc.identifier.isi | WOS:000393599700032 | - |