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Article: A New Coordinating Chiral Lithium Amide

TitleA New Coordinating Chiral Lithium Amide
Authors
Issue Date1989
Citation
Angewandte Chemie International Edition in English, 1989, v. 28, n. 8, p. 1044-1047 How to Cite?
AbstractThe C2‐symmetric (R,R)‐di(α‐methoxymethylbenzyl)amine 1, synthesized from (R)‐phenylglycinol and α‐methoxyacetophenone, yields a lithium amide 2 upon lithiation with nBuLi. In the solid state and in solution, 2 is present as a dimer. 4‐tert‐Butylcyclohexanone could be asymmetrically deprotonated with this lithium amide. (Figure Presented.) Copyright © 1989 by VCH Verlagsgesellschaft mbH, Germany
Persistent Identifierhttp://hdl.handle.net/10722/333232
ISSN
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorBarr, Donald-
dc.contributor.authorBerrisford, David J.-
dc.contributor.authorJones, Raymond V.H.-
dc.contributor.authorSlawin, Alexandra M.Z.-
dc.contributor.authorSnaith, Ronald-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:17:43Z-
dc.date.available2023-10-06T05:17:43Z-
dc.date.issued1989-
dc.identifier.citationAngewandte Chemie International Edition in English, 1989, v. 28, n. 8, p. 1044-1047-
dc.identifier.issn0570-0833-
dc.identifier.urihttp://hdl.handle.net/10722/333232-
dc.description.abstractThe C2‐symmetric (R,R)‐di(α‐methoxymethylbenzyl)amine 1, synthesized from (R)‐phenylglycinol and α‐methoxyacetophenone, yields a lithium amide 2 upon lithiation with nBuLi. In the solid state and in solution, 2 is present as a dimer. 4‐tert‐Butylcyclohexanone could be asymmetrically deprotonated with this lithium amide. (Figure Presented.) Copyright © 1989 by VCH Verlagsgesellschaft mbH, Germany-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie International Edition in English-
dc.titleA New Coordinating Chiral Lithium Amide-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.198910441-
dc.identifier.scopuseid_2-s2.0-84990165959-
dc.identifier.volume28-
dc.identifier.issue8-
dc.identifier.spage1044-
dc.identifier.epage1047-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:A1989AN46800024-

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