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- Publisher Website: 10.1002/anie.198706931
- Scopus: eid_2-s2.0-84985634188
- WOS: WOS:A1987J644200028
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Article: Macrobicyclic Polyethers as Second Sphere Ligands for Tetraammineplatinum(II)
| Title | Macrobicyclic Polyethers as Second Sphere Ligands for Tetraammineplatinum(II) |
|---|---|
| Authors | |
| Issue Date | 1987 |
| Citation | Angewandte Chemie International Edition in English, 1987, v. 26, n. 7, p. 693-696 How to Cite? |
| Abstract | A T‐arrangement of two benzene rings contributes—aside from H‐bridges—to the stabilization of a 2:1 adduct of the molecular receptor 2 with [Pt(NH3)4]2⊕ in the solid state (X‐ray structure analysis); in [D6]acetone only a 1:1 adduct is present (1H‐NMR). With the same cation, 1 forms only 1:1 adducts in solution and in the solid state. Thus, small changes in the ligands can drastically alter its bonding properties (1, R H; 2, R Me). (Figure Presented.) Copyright © 1987 by VCH Verlagsgesellschaft mbH, Germany |
| Persistent Identifier | http://hdl.handle.net/10722/333212 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Alston, David R. | - |
| dc.contributor.author | Slawin, Alexandra M.Z. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.contributor.author | Williams, David J. | - |
| dc.contributor.author | Zarzycki, Ryszard | - |
| dc.date.accessioned | 2023-10-06T05:17:34Z | - |
| dc.date.available | 2023-10-06T05:17:34Z | - |
| dc.date.issued | 1987 | - |
| dc.identifier.citation | Angewandte Chemie International Edition in English, 1987, v. 26, n. 7, p. 693-696 | - |
| dc.identifier.issn | 0570-0833 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/333212 | - |
| dc.description.abstract | A T‐arrangement of two benzene rings contributes—aside from H‐bridges—to the stabilization of a 2:1 adduct of the molecular receptor 2 with [Pt(NH3)4]2⊕ in the solid state (X‐ray structure analysis); in [D6]acetone only a 1:1 adduct is present (1H‐NMR). With the same cation, 1 forms only 1:1 adducts in solution and in the solid state. Thus, small changes in the ligands can drastically alter its bonding properties (1, R H; 2, R Me). (Figure Presented.) Copyright © 1987 by VCH Verlagsgesellschaft mbH, Germany | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie International Edition in English | - |
| dc.title | Macrobicyclic Polyethers as Second Sphere Ligands for Tetraammineplatinum(II) | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.198706931 | - |
| dc.identifier.scopus | eid_2-s2.0-84985634188 | - |
| dc.identifier.volume | 26 | - |
| dc.identifier.issue | 7 | - |
| dc.identifier.spage | 693 | - |
| dc.identifier.epage | 696 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:A1987J644200028 | - |