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Article: Crown Ether Complexes of Sulfonium Salts—The X‐Ray Crystal Structures of [PhCOCH2SMe2·[18]Crown‐6]n[PF6]n and [(PhCOCHPhSMe2)2·[18]Crown‐6][PF6]2

TitleCrown Ether Complexes of Sulfonium Salts—The X‐Ray Crystal Structures of [PhCOCH<inf>2</inf>SMe<inf>2</inf>·[18]Crown‐6]<inf>n</inf>[PF<inf>6</inf>]<inf>n</inf> and [(PhCOCHPhSMe<inf>2</inf>)<inf>2</inf>·[18]Crown‐6][PF<inf>6</inf>]<inf>2</inf>
Authors
Allwood, Billy L.Crosby, JohnPears, David A.Stoddart, J. FraserWilliams, David J.
Issue Date1984
Citation
Angewandte Chemie International Edition in English, 1984, v. 23, n. 12, p. 977-979 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.198409771
AbstractThe transformation of polymeric into discrete host‐guest complexes takes place on replacement of a methylene H‐atom in the sulfonium ion of the [18]‐crown‐6 (18C6) complex 1 by a bulky group such as phenyl. The dication of 2 exhibits a sort of sandwich structure (sulfonium ion‐crown ether‐sulfonium ion); the bonding between guest cations on the one hand and crown ethers on the other derives from different H‐bridges; a peculiarity is the formation of the “bifurcated” H‐bridges. (Formula Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany
Persistent Identifierhttp://hdl.handle.net/10722/333210
ISSN
0570-0833
ISI Accession Number ID
WOS:A1984AAZ2800018

 

DC FieldValueLanguage
dc.contributor.authorAllwood, Billy L.-
dc.contributor.authorCrosby, John-
dc.contributor.authorPears, David A.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:17:33Z-
dc.date.available2023-10-06T05:17:33Z-
dc.date.issued1984-
dc.identifier.citationAngewandte Chemie International Edition in English, 1984, v. 23, n. 12, p. 977-979-
dc.identifier.issn0570-0833-
dc.identifier.urihttp://hdl.handle.net/10722/333210-
dc.description.abstractThe transformation of polymeric into discrete host‐guest complexes takes place on replacement of a methylene H‐atom in the sulfonium ion of the [18]‐crown‐6 (18C6) complex 1 by a bulky group such as phenyl. The dication of 2 exhibits a sort of sandwich structure (sulfonium ion‐crown ether‐sulfonium ion); the bonding between guest cations on the one hand and crown ethers on the other derives from different H‐bridges; a peculiarity is the formation of the “bifurcated” H‐bridges. (Formula Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie International Edition in English-
dc.titleCrown Ether Complexes of Sulfonium Salts—The X‐Ray Crystal Structures of [PhCOCH<inf>2</inf>SMe<inf>2</inf>·[18]Crown‐6]<inf>n</inf>[PF<inf>6</inf>]<inf>n</inf> and [(PhCOCHPhSMe<inf>2</inf>)<inf>2</inf>·[18]Crown‐6][PF<inf>6</inf>]<inf>2</inf>-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.198409771-
dc.identifier.scopuseid_2-s2.0-84985633555-
dc.identifier.volume23-
dc.identifier.issue12-
dc.identifier.spage977-
dc.identifier.epage979-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:A1984AAZ2800018-

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