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Article: Crown Ether Complexes of Phosphonium Salts — The X‐Ray Structure Analysis of [(Ph3PMe)2·[18]Crown‐6][PF6]2

TitleCrown Ether Complexes of Phosphonium Salts — The X‐Ray Structure Analysis of [(Ph<inf>3</inf>PMe)<inf>2</inf>·[18]Crown‐6][PF<inf>6</inf>]<inf>2</inf>
Authors
Allwood, Billy L.Colquhoun, Howard M.Crosby, JohnPears, David A.Stoddart, J. FraserWilliams, David J.
Issue Date1984
Citation
Angewandte Chemie International Edition in English, 1984, v. 23, n. 10, p. 824-825 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.198408241
AbstractA higly symmetric cation consisting of two phosphonium ions and a crown ether molecule is obtained in crystalline 1. In 1 the direction PMe…Me′P′ coincides with the symmetry axis; the 18C6 host is oriented at right angles to this. All methyl H atoms are bound by discrete H bridges at individual O atoms. These H bridges are in each case directed towards the “rear side” of the crown ether ring. (Formula Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany
Persistent Identifierhttp://hdl.handle.net/10722/333209
ISSN
0570-0833
ISI Accession Number ID
WOS:A1984TU99300027

 

DC FieldValueLanguage
dc.contributor.authorAllwood, Billy L.-
dc.contributor.authorColquhoun, Howard M.-
dc.contributor.authorCrosby, John-
dc.contributor.authorPears, David A.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:17:32Z-
dc.date.available2023-10-06T05:17:32Z-
dc.date.issued1984-
dc.identifier.citationAngewandte Chemie International Edition in English, 1984, v. 23, n. 10, p. 824-825-
dc.identifier.issn0570-0833-
dc.identifier.urihttp://hdl.handle.net/10722/333209-
dc.description.abstractA higly symmetric cation consisting of two phosphonium ions and a crown ether molecule is obtained in crystalline 1. In 1 the direction PMe…Me′P′ coincides with the symmetry axis; the 18C6 host is oriented at right angles to this. All methyl H atoms are bound by discrete H bridges at individual O atoms. These H bridges are in each case directed towards the “rear side” of the crown ether ring. (Formula Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie International Edition in English-
dc.titleCrown Ether Complexes of Phosphonium Salts — The X‐Ray Structure Analysis of [(Ph<inf>3</inf>PMe)<inf>2</inf>·[18]Crown‐6][PF<inf>6</inf>]<inf>2</inf>-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.198408241-
dc.identifier.scopuseid_2-s2.0-84985616394-
dc.identifier.volume23-
dc.identifier.issue10-
dc.identifier.spage824-
dc.identifier.epage825-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:A1984TU99300027-

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