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Article: Cyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X‐Ray Crystal Structure of [Rh(cod)(NH3)2·α‐cyclodextrin][PF6]·6H2O

TitleCyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X‐Ray Crystal Structure of [Rh(cod)(NH<inf>3</inf>)<inf>2</inf>·α‐cyclodextrin][PF<inf>6</inf>]·6H<inf>2</inf>O
Authors
Alston, David R.Slawin, Alexandra M.Z.Stoddart, J. FraserWilliams, David J.
Issue Date1985
Citation
Angewandte Chemie International Edition in English, 1985, v. 24, n. 9, p. 786-787 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.198507861
AbstractThe structure of the 1:1 adduct of [Rh(cod)(NH3)2][PF6] (cod = 1,5‐cyclooctadiene) and α‐cyclodextrin (α‐CD) has been elucidated by an X‐ray structure analysis. The tub‐shaped cod ligand lies almost exactly above the center of the α‐CD cavity, into which it partilly protudes. The two NH3 ligands interact with four secondary OH groups. (Figure Presented.) Copyright © 1985 by VCH Verlagsgesellschaft mbH, Germany
Persistent Identifierhttp://hdl.handle.net/10722/333208
ISSN
0570-0833
ISI Accession Number ID
WOS:A1985ATV5200025

 

DC FieldValueLanguage
dc.contributor.authorAlston, David R.-
dc.contributor.authorSlawin, Alexandra M.Z.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:17:32Z-
dc.date.available2023-10-06T05:17:32Z-
dc.date.issued1985-
dc.identifier.citationAngewandte Chemie International Edition in English, 1985, v. 24, n. 9, p. 786-787-
dc.identifier.issn0570-0833-
dc.identifier.urihttp://hdl.handle.net/10722/333208-
dc.description.abstractThe structure of the 1:1 adduct of [Rh(cod)(NH3)2][PF6] (cod = 1,5‐cyclooctadiene) and α‐cyclodextrin (α‐CD) has been elucidated by an X‐ray structure analysis. The tub‐shaped cod ligand lies almost exactly above the center of the α‐CD cavity, into which it partilly protudes. The two NH3 ligands interact with four secondary OH groups. (Figure Presented.) Copyright © 1985 by VCH Verlagsgesellschaft mbH, Germany-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie International Edition in English-
dc.titleCyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X‐Ray Crystal Structure of [Rh(cod)(NH<inf>3</inf>)<inf>2</inf>·α‐cyclodextrin][PF<inf>6</inf>]·6H<inf>2</inf>O-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.198507861-
dc.identifier.scopuseid_2-s2.0-84985609687-
dc.identifier.volume24-
dc.identifier.issue9-
dc.identifier.spage786-
dc.identifier.epage787-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:A1985ATV5200025-

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