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- Publisher Website: 10.1002/anie.198110511
- Scopus: eid_2-s2.0-84985510227
- WOS: WOS:A1981MZ50300036
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Article: Second Sphere Coordination of Cationic Platinum Complexes by Crown Ethers— The X‐Ray Crystal Structure of [Pt(bpy)(NH3 )2 . Dibenzo[30]crown‐10]2+[PF6 ] 2−xH2 O (x≈0.6)
| Title | Second Sphere Coordination of Cationic Platinum Complexes by Crown Ethers— The X‐Ray Crystal Structure of [Pt(bpy)(NH<inf>3</inf>)<inf>2</inf>. Dibenzo[30]crown‐10]<sup>2+</sup>[PF<inf>6</inf>] 2−xH<inf>2</inf>O (x≈0.6) |
|---|---|
| Authors | |
| Issue Date | 1981 |
| Citation | Angewandte Chemie International Edition in English, 1981, v. 20, n. 12, p. 1051-1053 How to Cite? |
| Abstract | Hydrogen bonding and charge‐transfer interactions stabilize the crystalline 1:1 adduct of [Pt(bpy)(NH3)2]2+[PF6]− and dlbenzo‐30‐crown‐10. An X‐ray structure analysis showed that the crown ether envelopes the dication; this coordination in the second sphere, which‐as UV and 1H‐NMR data show—also exists in solution, is to a great extent made possible by interactions between the two benzene rings of the host molecule and a pyridine ring of the guest complex. (Figure Presented.) Copyright © 1981 by Verlag Chemie, GmbH, Germany |
| Persistent Identifier | http://hdl.handle.net/10722/333204 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Colquhoun, Howard M. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.contributor.author | Williams, David J. | - |
| dc.contributor.author | Wolstenholme, John B. | - |
| dc.contributor.author | Zarzycki, Ryszard | - |
| dc.date.accessioned | 2023-10-06T05:17:30Z | - |
| dc.date.available | 2023-10-06T05:17:30Z | - |
| dc.date.issued | 1981 | - |
| dc.identifier.citation | Angewandte Chemie International Edition in English, 1981, v. 20, n. 12, p. 1051-1053 | - |
| dc.identifier.issn | 0570-0833 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/333204 | - |
| dc.description.abstract | Hydrogen bonding and charge‐transfer interactions stabilize the crystalline 1:1 adduct of [Pt(bpy)(NH3)2]2+[PF6]− and dlbenzo‐30‐crown‐10. An X‐ray structure analysis showed that the crown ether envelopes the dication; this coordination in the second sphere, which‐as UV and 1H‐NMR data show—also exists in solution, is to a great extent made possible by interactions between the two benzene rings of the host molecule and a pyridine ring of the guest complex. (Figure Presented.) Copyright © 1981 by Verlag Chemie, GmbH, Germany | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie International Edition in English | - |
| dc.title | Second Sphere Coordination of Cationic Platinum Complexes by Crown Ethers— The X‐Ray Crystal Structure of [Pt(bpy)(NH<inf>3</inf>)<inf>2</inf>. Dibenzo[30]crown‐10]<sup>2+</sup>[PF<inf>6</inf>] 2−xH<inf>2</inf>O (x≈0.6) | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.198110511 | - |
| dc.identifier.scopus | eid_2-s2.0-84985510227 | - |
| dc.identifier.volume | 20 | - |
| dc.identifier.issue | 12 | - |
| dc.identifier.spage | 1051 | - |
| dc.identifier.epage | 1053 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:A1981MZ50300036 | - |