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Article: A metal-organic framework immobilised iridium pincer complex

TitleA metal-organic framework immobilised iridium pincer complex
Authors
Issue Date2016
Citation
Chemical Science, 2016, v. 7, n. 8, p. 4980-4984 How to Cite?
AbstractAn iridium pincer complex has been immobilised in the metal-organic framework NU-1000 using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formation of the catalytically active iridium dihydride. The Ir-pincer modified NU-1000 is an active catalyst for the condensed phase hydrogenation of a liquid alkene (1-decene and styrene) and shows enhanced activity with respect to a homogeneous analogue. Additionally, the Ir-pincer immobilised inside NU-1000 operated as an efficient heterogenous catalyst under flow conditions.
Persistent Identifierhttp://hdl.handle.net/10722/333187
ISSN
2023 Impact Factor: 7.6
2023 SCImago Journal Rankings: 2.333
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorRimoldi, Martino-
dc.contributor.authorNakamura, Akitake-
dc.contributor.authorVermeulen, Nicolaas A.-
dc.contributor.authorHenkelis, James J.-
dc.contributor.authorBlackburn, Anthea K.-
dc.contributor.authorHupp, Joseph T.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorFarha, Omar K.-
dc.date.accessioned2023-10-06T05:17:22Z-
dc.date.available2023-10-06T05:17:22Z-
dc.date.issued2016-
dc.identifier.citationChemical Science, 2016, v. 7, n. 8, p. 4980-4984-
dc.identifier.issn2041-6520-
dc.identifier.urihttp://hdl.handle.net/10722/333187-
dc.description.abstractAn iridium pincer complex has been immobilised in the metal-organic framework NU-1000 using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formation of the catalytically active iridium dihydride. The Ir-pincer modified NU-1000 is an active catalyst for the condensed phase hydrogenation of a liquid alkene (1-decene and styrene) and shows enhanced activity with respect to a homogeneous analogue. Additionally, the Ir-pincer immobilised inside NU-1000 operated as an efficient heterogenous catalyst under flow conditions.-
dc.languageeng-
dc.relation.ispartofChemical Science-
dc.titleA metal-organic framework immobilised iridium pincer complex-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c6sc01376g-
dc.identifier.scopuseid_2-s2.0-84979703305-
dc.identifier.volume7-
dc.identifier.issue8-
dc.identifier.spage4980-
dc.identifier.epage4984-
dc.identifier.eissn2041-6539-
dc.identifier.isiWOS:000380893900023-

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