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Article: An Electrochromic Tristable Molecular Switch

TitleAn Electrochromic Tristable Molecular Switch
Authors
Issue Date2015
Citation
Journal of the American Chemical Society, 2015, v. 137, n. 42, p. 13484-13487 How to Cite?
AbstractA tristable [2]catenane, composed of a macrocyclic polyether incorporating 1,5-dioxynaphthalene (DNP) and tetrathiafulvalene (TTF) units along with a 4,4′-bipyridinium (BIPY•+) radical cation as three very different potential recognition sites, interlocked mechanically with the tetracationic cyclophane, cyclobis(paraquat-p-phenylene) (CBPQT4+), was synthesized by donor-acceptor templation, employing a "threading-followed-by-cyclization" approach. In this catenane, movement of the CBPQT4+ ring in its different redox states among these three potential recognition sites, with corresponding color changes, is achieved by tuning external redox potentials. In the starting state, where no external potential is applied, the ring encircles the TTF unit and displays a green color. Upon oxidation of the TTF unit, the CBPQT4+ ring moves to the DNP unit, producing a red color. Finally, if all the BIPY2+ units are reduced to BIPY•+ radical cations, the resulting CBPQT2(•+) diradical dication will migrate to the BIPY•+ unit, resulting in a purple color. These readily switchable electrochromic properties render the [2]catenane attractive for use in electro-optical devices.
Persistent Identifierhttp://hdl.handle.net/10722/333144
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorSun, Junling-
dc.contributor.authorWu, Yilei-
dc.contributor.authorWang, Yuping-
dc.contributor.authorLiu, Zhichang-
dc.contributor.authorCheng, Chuyang-
dc.contributor.authorHartlieb, Karel J.-
dc.contributor.authorWasielewski, Michael R.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:17:03Z-
dc.date.available2023-10-06T05:17:03Z-
dc.date.issued2015-
dc.identifier.citationJournal of the American Chemical Society, 2015, v. 137, n. 42, p. 13484-13487-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/333144-
dc.description.abstractA tristable [2]catenane, composed of a macrocyclic polyether incorporating 1,5-dioxynaphthalene (DNP) and tetrathiafulvalene (TTF) units along with a 4,4′-bipyridinium (BIPY•+) radical cation as three very different potential recognition sites, interlocked mechanically with the tetracationic cyclophane, cyclobis(paraquat-p-phenylene) (CBPQT4+), was synthesized by donor-acceptor templation, employing a "threading-followed-by-cyclization" approach. In this catenane, movement of the CBPQT4+ ring in its different redox states among these three potential recognition sites, with corresponding color changes, is achieved by tuning external redox potentials. In the starting state, where no external potential is applied, the ring encircles the TTF unit and displays a green color. Upon oxidation of the TTF unit, the CBPQT4+ ring moves to the DNP unit, producing a red color. Finally, if all the BIPY2+ units are reduced to BIPY•+ radical cations, the resulting CBPQT2(•+) diradical dication will migrate to the BIPY•+ unit, resulting in a purple color. These readily switchable electrochromic properties render the [2]catenane attractive for use in electro-optical devices.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleAn Electrochromic Tristable Molecular Switch-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jacs.5b09274-
dc.identifier.scopuseid_2-s2.0-84945969212-
dc.identifier.volume137-
dc.identifier.issue42-
dc.identifier.spage13484-
dc.identifier.epage13487-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000363916600012-

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