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Article: A Hafnium-Based Metal-Organic Framework as a Nature-Inspired Tandem Reaction Catalyst

TitleA Hafnium-Based Metal-Organic Framework as a Nature-Inspired Tandem Reaction Catalyst
Authors
Beyzavi, M. HassanVermeulen, Nicolaas A.Howarth, Ashlee J.Tussupbayev, SamatLeague, Aaron B.Schweitzer, Neil M.Gallagher, James R.Platero-Prats, Ana E.Hafezi, NemaSarjeant, Amy A.Miller, Jeffrey T.Chapman, Karena W.Stoddart, J. FraserCramer, Christopher J.Hupp, Joseph T.Farha, Omar K.
Issue Date2015
Citation
Journal of the American Chemical Society, 2015, v. 137, n. 42, p. 13624-13631 How to Cite?
DOI: http://dx.doi.org/10.1021/jacs.5b08440
AbstractTandem catalytic systems, often inspired by biological systems, offer many advantages in the formation of highly functionalized small molecules. Herein, a new metal-organic framework (MOF) with porphyrinic struts and Hf6 nodes is reported. This MOF demonstrates catalytic efficacy in the tandem oxidation and functionalization of styrene utilizing molecular oxygen as a terminal oxidant. The product, a protected 1,2-aminoalcohol, is formed selectively and with high efficiency using this recyclable heterogeneous catalyst. Significantly, the unusual regioselective transformation occurs only when an Fe-decorated Hf6 node and the Fe-porphyrin strut work in concert. This report is an example of concurrent orthogonal tandem catalysis.
Persistent Identifierhttp://hdl.handle.net/10722/333143
ISSN
0002-7863
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489

 

DC FieldValueLanguage
dc.contributor.authorBeyzavi, M. Hassan-
dc.contributor.authorVermeulen, Nicolaas A.-
dc.contributor.authorHowarth, Ashlee J.-
dc.contributor.authorTussupbayev, Samat-
dc.contributor.authorLeague, Aaron B.-
dc.contributor.authorSchweitzer, Neil M.-
dc.contributor.authorGallagher, James R.-
dc.contributor.authorPlatero-Prats, Ana E.-
dc.contributor.authorHafezi, Nema-
dc.contributor.authorSarjeant, Amy A.-
dc.contributor.authorMiller, Jeffrey T.-
dc.contributor.authorChapman, Karena W.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorCramer, Christopher J.-
dc.contributor.authorHupp, Joseph T.-
dc.contributor.authorFarha, Omar K.-
dc.date.accessioned2023-10-06T05:17:03Z-
dc.date.available2023-10-06T05:17:03Z-
dc.date.issued2015-
dc.identifier.citationJournal of the American Chemical Society, 2015, v. 137, n. 42, p. 13624-13631-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/333143-
dc.description.abstractTandem catalytic systems, often inspired by biological systems, offer many advantages in the formation of highly functionalized small molecules. Herein, a new metal-organic framework (MOF) with porphyrinic struts and Hf6 nodes is reported. This MOF demonstrates catalytic efficacy in the tandem oxidation and functionalization of styrene utilizing molecular oxygen as a terminal oxidant. The product, a protected 1,2-aminoalcohol, is formed selectively and with high efficiency using this recyclable heterogeneous catalyst. Significantly, the unusual regioselective transformation occurs only when an Fe-decorated Hf6 node and the Fe-porphyrin strut work in concert. This report is an example of concurrent orthogonal tandem catalysis.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleA Hafnium-Based Metal-Organic Framework as a Nature-Inspired Tandem Reaction Catalyst-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jacs.5b08440-
dc.identifier.scopuseid_2-s2.0-84945937858-
dc.identifier.volume137-
dc.identifier.issue42-
dc.identifier.spage13624-
dc.identifier.epage13631-
dc.identifier.eissn1520-5126-

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