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Article: A Hafnium-Based Metal-Organic Framework as a Nature-Inspired Tandem Reaction Catalyst

TitleA Hafnium-Based Metal-Organic Framework as a Nature-Inspired Tandem Reaction Catalyst
Authors
Issue Date2015
Citation
Journal of the American Chemical Society, 2015, v. 137, n. 42, p. 13624-13631 How to Cite?
AbstractTandem catalytic systems, often inspired by biological systems, offer many advantages in the formation of highly functionalized small molecules. Herein, a new metal-organic framework (MOF) with porphyrinic struts and Hf6 nodes is reported. This MOF demonstrates catalytic efficacy in the tandem oxidation and functionalization of styrene utilizing molecular oxygen as a terminal oxidant. The product, a protected 1,2-aminoalcohol, is formed selectively and with high efficiency using this recyclable heterogeneous catalyst. Significantly, the unusual regioselective transformation occurs only when an Fe-decorated Hf6 node and the Fe-porphyrin strut work in concert. This report is an example of concurrent orthogonal tandem catalysis.
Persistent Identifierhttp://hdl.handle.net/10722/333143
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489

 

DC FieldValueLanguage
dc.contributor.authorBeyzavi, M. Hassan-
dc.contributor.authorVermeulen, Nicolaas A.-
dc.contributor.authorHowarth, Ashlee J.-
dc.contributor.authorTussupbayev, Samat-
dc.contributor.authorLeague, Aaron B.-
dc.contributor.authorSchweitzer, Neil M.-
dc.contributor.authorGallagher, James R.-
dc.contributor.authorPlatero-Prats, Ana E.-
dc.contributor.authorHafezi, Nema-
dc.contributor.authorSarjeant, Amy A.-
dc.contributor.authorMiller, Jeffrey T.-
dc.contributor.authorChapman, Karena W.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorCramer, Christopher J.-
dc.contributor.authorHupp, Joseph T.-
dc.contributor.authorFarha, Omar K.-
dc.date.accessioned2023-10-06T05:17:03Z-
dc.date.available2023-10-06T05:17:03Z-
dc.date.issued2015-
dc.identifier.citationJournal of the American Chemical Society, 2015, v. 137, n. 42, p. 13624-13631-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/333143-
dc.description.abstractTandem catalytic systems, often inspired by biological systems, offer many advantages in the formation of highly functionalized small molecules. Herein, a new metal-organic framework (MOF) with porphyrinic struts and Hf6 nodes is reported. This MOF demonstrates catalytic efficacy in the tandem oxidation and functionalization of styrene utilizing molecular oxygen as a terminal oxidant. The product, a protected 1,2-aminoalcohol, is formed selectively and with high efficiency using this recyclable heterogeneous catalyst. Significantly, the unusual regioselective transformation occurs only when an Fe-decorated Hf6 node and the Fe-porphyrin strut work in concert. This report is an example of concurrent orthogonal tandem catalysis.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleA Hafnium-Based Metal-Organic Framework as a Nature-Inspired Tandem Reaction Catalyst-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jacs.5b08440-
dc.identifier.scopuseid_2-s2.0-84945937858-
dc.identifier.volume137-
dc.identifier.issue42-
dc.identifier.spage13624-
dc.identifier.epage13631-
dc.identifier.eissn1520-5126-

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