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Article: Aromatizing olefin metathesis by ligand isolation inside a metal- organic framework

TitleAromatizing olefin metathesis by ligand isolation inside a metal- organic framework
Authors
Vermeulen, Nicolaas A.Karagiaridi, OlgaSarjeant, Amy A.Stern, Charlotte L.Hupp, Joseph T.Farha, Omar K.Stoddart, J. Fraser
Issue Date2013
Citation
Journal of the American Chemical Society, 2013, v. 135, n. 40, p. 14916-14919 How to Cite?
DOI: http://dx.doi.org/10.1021/ja407333q
AbstractThe aromatizing ring-closing metathesis has been shown to take place inside an extended porous framework. Employing a combination of solvent-assisted linker exchange and postsynthesis modification using olefin metathesis, the noninterpenetrated SALEM-14 was formed and converted catalytically into PAH-MOF-1 with polycyclic aromatic hydrocarbon (PAH) pillars. The metal-organic framework in SALEM-14 prevents "intermolecular" olefin metathesis from occurring between the pillars in the presence of the first generation Hoveyda-Grubbs catalyst, while favoring the production of a PAH, which can be released from the framework under acidic conditions in dimethylsulfoxide. © 2013 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/333045
ISSN
0002-7863
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID
WOS:000326356400006

 

DC FieldValueLanguage
dc.contributor.authorVermeulen, Nicolaas A.-
dc.contributor.authorKaragiaridi, Olga-
dc.contributor.authorSarjeant, Amy A.-
dc.contributor.authorStern, Charlotte L.-
dc.contributor.authorHupp, Joseph T.-
dc.contributor.authorFarha, Omar K.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:16:19Z-
dc.date.available2023-10-06T05:16:19Z-
dc.date.issued2013-
dc.identifier.citationJournal of the American Chemical Society, 2013, v. 135, n. 40, p. 14916-14919-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/333045-
dc.description.abstractThe aromatizing ring-closing metathesis has been shown to take place inside an extended porous framework. Employing a combination of solvent-assisted linker exchange and postsynthesis modification using olefin metathesis, the noninterpenetrated SALEM-14 was formed and converted catalytically into PAH-MOF-1 with polycyclic aromatic hydrocarbon (PAH) pillars. The metal-organic framework in SALEM-14 prevents "intermolecular" olefin metathesis from occurring between the pillars in the presence of the first generation Hoveyda-Grubbs catalyst, while favoring the production of a PAH, which can be released from the framework under acidic conditions in dimethylsulfoxide. © 2013 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleAromatizing olefin metathesis by ligand isolation inside a metal- organic framework-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja407333q-
dc.identifier.scopuseid_2-s2.0-84885586612-
dc.identifier.volume135-
dc.identifier.issue40-
dc.identifier.spage14916-
dc.identifier.epage14919-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000326356400006-

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