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Article: Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework

TitleIncorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework
Authors
Issue Date2012
Citation
Journal of the American Chemical Society, 2012, v. 134, n. 42, p. 17436-17439 How to Cite?
AbstractAn efficient synthetic route to an A1/A2-difunctionalized pillar[5]arene containing resolvable planar chirality has been developed and the arene employed as a strut in the synthesis of P5A-MOF-1, which has been demonstrated by X-ray powder diffraction analysis-supported by modeling-to be isoreticular with MOF-5. This metal-organic framework has an active domain that expresses good and selective uptake of neutral and positively charged electron-poor aromatic guests, which effect color changes of the cubic crystals from faint yellow to deep orange, arising from charge transfer between the guests and active domain of P5A-MOF-1. © 2012 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/333005
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorStrutt, Nathan L.-
dc.contributor.authorFairen-Jimenez, David-
dc.contributor.authorIehl, Julien-
dc.contributor.authorLalonde, Marianne B.-
dc.contributor.authorSnurr, Randall Q.-
dc.contributor.authorFarha, Omar K.-
dc.contributor.authorHupp, Joseph T.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:16:02Z-
dc.date.available2023-10-06T05:16:02Z-
dc.date.issued2012-
dc.identifier.citationJournal of the American Chemical Society, 2012, v. 134, n. 42, p. 17436-17439-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/333005-
dc.description.abstractAn efficient synthetic route to an A1/A2-difunctionalized pillar[5]arene containing resolvable planar chirality has been developed and the arene employed as a strut in the synthesis of P5A-MOF-1, which has been demonstrated by X-ray powder diffraction analysis-supported by modeling-to be isoreticular with MOF-5. This metal-organic framework has an active domain that expresses good and selective uptake of neutral and positively charged electron-poor aromatic guests, which effect color changes of the cubic crystals from faint yellow to deep orange, arising from charge transfer between the guests and active domain of P5A-MOF-1. © 2012 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleIncorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja3082523-
dc.identifier.scopuseid_2-s2.0-84867809310-
dc.identifier.volume134-
dc.identifier.issue42-
dc.identifier.spage17436-
dc.identifier.epage17439-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000310103800027-

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