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Article: Polyporous metal-coordination frameworks

TitlePolyporous metal-coordination frameworks
Authors
Gassensmith, Jeremiah J.Smaldone, Ronald A.Forgan, Ross S.Wilmer, Christopher E.Cordes, David B.Botros, Youssry Y.Slawin, Alexandra M.Z.Snurr, Randall Q.Stoddart, J. Fraser
Issue Date2012
Citation
Organic Letters, 2012, v. 14, n. 6, p. 1460-1463 How to Cite?
DOI: http://dx.doi.org/10.1021/ol300199a
AbstractStarting from a chiral building block - α-cyclodextrin - and rubidium salts, the crystallization of a complex of chiral helices, which constitute a "green" porous coordination polymer, has been realized. Cyclodextrin molecules coordinated by rubidium ions form porous, infinitely long left-handed helical channels, interdigitated with each other. A theoretical examination of the potential of this new material to act as a medium for chiral separation is presented. © 2012 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/332972
ISSN
1523-7060
2023 Impact Factor: 4.9
2023 SCImago Journal Rankings: 1.245
ISI Accession Number ID
WOS:000301516000026

 

DC FieldValueLanguage
dc.contributor.authorGassensmith, Jeremiah J.-
dc.contributor.authorSmaldone, Ronald A.-
dc.contributor.authorForgan, Ross S.-
dc.contributor.authorWilmer, Christopher E.-
dc.contributor.authorCordes, David B.-
dc.contributor.authorBotros, Youssry Y.-
dc.contributor.authorSlawin, Alexandra M.Z.-
dc.contributor.authorSnurr, Randall Q.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:15:45Z-
dc.date.available2023-10-06T05:15:45Z-
dc.date.issued2012-
dc.identifier.citationOrganic Letters, 2012, v. 14, n. 6, p. 1460-1463-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/332972-
dc.description.abstractStarting from a chiral building block - α-cyclodextrin - and rubidium salts, the crystallization of a complex of chiral helices, which constitute a "green" porous coordination polymer, has been realized. Cyclodextrin molecules coordinated by rubidium ions form porous, infinitely long left-handed helical channels, interdigitated with each other. A theoretical examination of the potential of this new material to act as a medium for chiral separation is presented. © 2012 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofOrganic Letters-
dc.titlePolyporous metal-coordination frameworks-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol300199a-
dc.identifier.pmid22375911-
dc.identifier.scopuseid_2-s2.0-84858641772-
dc.identifier.volume14-
dc.identifier.issue6-
dc.identifier.spage1460-
dc.identifier.epage1463-
dc.identifier.eissn1523-7052-
dc.identifier.isiWOS:000301516000026-

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