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- Publisher Website: 10.1039/c005424k
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Article: Solution-phase counterion effects in supramolecular and mechanostereochemical systems
Title | Solution-phase counterion effects in supramolecular and mechanostereochemical systems |
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Authors | |
Issue Date | 2011 |
Citation | Chemical Society Reviews, 2011, v. 40, n. 1, p. 57-78 How to Cite? |
Abstract | The self-assembly of molecular components into complex superstructures involves the subtle interplay of various noncovalent forces. Charged species are often utilised in self-assembly processes as a result of the favorable π–π, cation–π, electrostatic, and hydrogen bonding interactions that form between these species. Although the counterions associated with these charged species can exert significant effects on the synthesis, stability, and operation of superstructures in solution, rarely are the counterions considered, leading to misinterpretations and misunderstandings of the studied systems. In this tutorial review, we discuss a variety of solution-phase counterion effects, from the fundamental origins to innovative ways in which these effects are exploited for useful functions. © 2011 The Royal Society of Chemistry. |
Persistent Identifier | http://hdl.handle.net/10722/332930 |
ISSN | 2023 Impact Factor: 40.4 2023 SCImago Journal Rankings: 12.511 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Gasa, Travis B. | - |
dc.contributor.author | Valente, Cory | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.date.accessioned | 2023-10-06T05:15:26Z | - |
dc.date.available | 2023-10-06T05:15:26Z | - |
dc.date.issued | 2011 | - |
dc.identifier.citation | Chemical Society Reviews, 2011, v. 40, n. 1, p. 57-78 | - |
dc.identifier.issn | 0306-0012 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332930 | - |
dc.description.abstract | The self-assembly of molecular components into complex superstructures involves the subtle interplay of various noncovalent forces. Charged species are often utilised in self-assembly processes as a result of the favorable π–π, cation–π, electrostatic, and hydrogen bonding interactions that form between these species. Although the counterions associated with these charged species can exert significant effects on the synthesis, stability, and operation of superstructures in solution, rarely are the counterions considered, leading to misinterpretations and misunderstandings of the studied systems. In this tutorial review, we discuss a variety of solution-phase counterion effects, from the fundamental origins to innovative ways in which these effects are exploited for useful functions. © 2011 The Royal Society of Chemistry. | - |
dc.language | eng | - |
dc.relation.ispartof | Chemical Society Reviews | - |
dc.title | Solution-phase counterion effects in supramolecular and mechanostereochemical systems | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/c005424k | - |
dc.identifier.scopus | eid_2-s2.0-78650339757 | - |
dc.identifier.volume | 40 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 57 | - |
dc.identifier.epage | 78 | - |
dc.identifier.eissn | 1460-4744 | - |
dc.identifier.isi | WOS:000285390900005 | - |