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- Publisher Website: 10.1002/anie.201004488
- Scopus: eid_2-s2.0-78249272655
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Article: Mechanical bond formation by radical templation
| Title | Mechanical bond formation by radical templation |
|---|---|
| Authors | |
| Keywords | Electrochemistry Radical dimerization Rotaxanes Self-assembly Template-directed synthesis |
| Issue Date | 2010 |
| Citation | Angewandte Chemie - International Edition, 2010, v. 49, n. 44, p. 8260-8265 How to Cite? |
| Abstract | A radical interaction has been employed as the recognition motif in the template-directed synthesis of a [2]rotaxane composed of cyclobis(paraquat-p- phenylene) and a viologen derivative. The ruthenium tris(bipyridine)/ triethanolamine system is used as the electron-transfer photocatalyst to generate the necessary radical cation components that result in the formation of an inclusion complex. A stoppering reaction follows to form the mechanical bond. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Persistent Identifier | http://hdl.handle.net/10722/332925 |
| ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Li, Hao | - |
| dc.contributor.author | Fahrenbach, Albert C. | - |
| dc.contributor.author | Dey, Sanjeev K. | - |
| dc.contributor.author | Basu, Subhadeep | - |
| dc.contributor.author | Trabolsi, Ali | - |
| dc.contributor.author | Zhu, Zhixue | - |
| dc.contributor.author | Botros, Youssry Y. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.date.accessioned | 2023-10-06T05:15:24Z | - |
| dc.date.available | 2023-10-06T05:15:24Z | - |
| dc.date.issued | 2010 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2010, v. 49, n. 44, p. 8260-8265 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332925 | - |
| dc.description.abstract | A radical interaction has been employed as the recognition motif in the template-directed synthesis of a [2]rotaxane composed of cyclobis(paraquat-p- phenylene) and a viologen derivative. The ruthenium tris(bipyridine)/ triethanolamine system is used as the electron-transfer photocatalyst to generate the necessary radical cation components that result in the formation of an inclusion complex. A stoppering reaction follows to form the mechanical bond. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | Electrochemistry | - |
| dc.subject | Radical dimerization | - |
| dc.subject | Rotaxanes | - |
| dc.subject | Self-assembly | - |
| dc.subject | Template-directed synthesis | - |
| dc.title | Mechanical bond formation by radical templation | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.201004488 | - |
| dc.identifier.scopus | eid_2-s2.0-78249272655 | - |
| dc.identifier.volume | 49 | - |
| dc.identifier.issue | 44 | - |
| dc.identifier.spage | 8260 | - |
| dc.identifier.epage | 8265 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:000284009100041 | - |