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- Publisher Website: 10.1039/c39810000430
- Scopus: eid_2-s2.0-37049099483
- WOS: WOS:A1981LP46800027
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Article: The solid state and solution conformational behaviour of a chiral 30-crown-10 derivative synthesised from 1,4:3,6-dianhydro-D-mannitol; X-ray crystal structure
Title | The solid state and solution conformational behaviour of a chiral 30-crown-10 derivative synthesised from 1,4:3,6-dianhydro-D-mannitol; X-ray crystal structure |
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Authors | |
Issue Date | 1981 |
Citation | Journal of the Chemical Society, Chemical Communications, 1981, n. 9, p. 430-432 How to Cite? |
Abstract | A chiral 30-crown-10 derivative, DD-(2), has been prepared from 1,4:3,6-dianhydro-D-mannitol, D-(1), and shown by X-ray crystallography and dynamic 13C n.m.r. spectroscopy to adopt, in both the solid state and in solution, a 'face-to-back' conformation which must undergo substantial change in order to create the hydrophilic cavity necessary for the formation of complexes with Li+, Na+, K+, Rb+, NH4+, MeNH3+, and Bu tNH3+ ions. |
Persistent Identifier | http://hdl.handle.net/10722/332791 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Metcalfe, Janet C. | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.contributor.author | Jones, Geraint | - |
dc.contributor.author | Crawshaw, Thomas H. | - |
dc.contributor.author | Quick, Andrew | - |
dc.contributor.author | Williams, David J. | - |
dc.date.accessioned | 2023-10-06T05:14:18Z | - |
dc.date.available | 2023-10-06T05:14:18Z | - |
dc.date.issued | 1981 | - |
dc.identifier.citation | Journal of the Chemical Society, Chemical Communications, 1981, n. 9, p. 430-432 | - |
dc.identifier.issn | 0022-4936 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332791 | - |
dc.description.abstract | A chiral 30-crown-10 derivative, DD-(2), has been prepared from 1,4:3,6-dianhydro-D-mannitol, D-(1), and shown by X-ray crystallography and dynamic 13C n.m.r. spectroscopy to adopt, in both the solid state and in solution, a 'face-to-back' conformation which must undergo substantial change in order to create the hydrophilic cavity necessary for the formation of complexes with Li+, Na+, K+, Rb+, NH4+, MeNH3+, and Bu tNH3+ ions. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | - |
dc.title | The solid state and solution conformational behaviour of a chiral 30-crown-10 derivative synthesised from 1,4:3,6-dianhydro-D-mannitol; X-ray crystal structure | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/c39810000430 | - |
dc.identifier.scopus | eid_2-s2.0-37049099483 | - |
dc.identifier.issue | 9 | - |
dc.identifier.spage | 430 | - |
dc.identifier.epage | 432 | - |
dc.identifier.isi | WOS:A1981LP46800027 | - |