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Article: Enantioselective reductions of aromatic ketones with ammonia-borane complexes of chiral tetraphenyl-18-crown-6 derivatives

TitleEnantioselective reductions of aromatic ketones with ammonia-borane complexes of chiral tetraphenyl-18-crown-6 derivatives
Authors
Allwood, Billy L.Shahriari-Zavareh, HooshangStoddart, J. FraserWilliams, David J.
Issue Date1984
Citation
Journal of the Chemical Society, Chemical Communications, 1984, n. 22, p. 1461-1464 How to Cite?
DOI: http://dx.doi.org/10.1039/C39840001461
AbstractEnantioselective reductions of prochiral aromatic ketones with adducts formed between ammonia-borane and (2R,3R,11R,12R)- and (2S,3S,11S,12S)- tetraphenyl-1,4,7,10,13,16-hexaoxacyclo-octadecane, (RRRR)-(3) and (SSSS)-(3), have afforded the corresponding (S) and (R) aromatic secondary alcohols with enantiomeric excesses of 20-67%.
Persistent Identifierhttp://hdl.handle.net/10722/332781
ISSN
0022-4936
ISI Accession Number ID
WOS:A1984TT62600001

 

DC FieldValueLanguage
dc.contributor.authorAllwood, Billy L.-
dc.contributor.authorShahriari-Zavareh, Hooshang-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:14:13Z-
dc.date.available2023-10-06T05:14:13Z-
dc.date.issued1984-
dc.identifier.citationJournal of the Chemical Society, Chemical Communications, 1984, n. 22, p. 1461-1464-
dc.identifier.issn0022-4936-
dc.identifier.urihttp://hdl.handle.net/10722/332781-
dc.description.abstractEnantioselective reductions of prochiral aromatic ketones with adducts formed between ammonia-borane and (2R,3R,11R,12R)- and (2S,3S,11S,12S)- tetraphenyl-1,4,7,10,13,16-hexaoxacyclo-octadecane, (RRRR)-(3) and (SSSS)-(3), have afforded the corresponding (S) and (R) aromatic secondary alcohols with enantiomeric excesses of 20-67%.-
dc.languageeng-
dc.relation.ispartofJournal of the Chemical Society, Chemical Communications-
dc.titleEnantioselective reductions of aromatic ketones with ammonia-borane complexes of chiral tetraphenyl-18-crown-6 derivatives-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/C39840001461-
dc.identifier.scopuseid_2-s2.0-37049091665-
dc.identifier.issue22-
dc.identifier.spage1461-
dc.identifier.epage1464-
dc.identifier.isiWOS:A1984TT62600001-

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