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Article: Complexation of Diquat by a bisparaphenylene-34-crown-10 derivative

TitleComplexation of Diquat by a bisparaphenylene-34-crown-10 derivative
Authors
Allwood, Billy L.Spencer, NeilShahriari-Zavareh, HooshangStoddart, J. FraserWilliams, David J.
Issue Date1987
Citation
Journal of the Chemical Society, Chemical Communications, 1987, n. 14, p. 1061-1064 How to Cite?
DOI: http://dx.doi.org/10.1039/C39870001061
AbstractX-Ray structural investigations of a bisparaphenylene-34-crown-10 derivative (BPP34C10) and its 1:1:1 complex with [Diquat][PF6] 2 and H2O reveal that, of two crystallographically independent conformations (I and II) both supporting large molecular cavities, one (II) retains its gross shape on complexation and interacts with the [Diquat]2+ dication by means of hydrogen and electrostatic bonds whilst accommodating weak charge transfer interactions and a hydrogen bonded H2O molecule within the docking constraints and microcavity, respectively, imposed by the more dominant non-covalent forces.
Persistent Identifierhttp://hdl.handle.net/10722/332770
ISSN
0022-4936
ISI Accession Number ID
WOS:A1987J524400007

 

DC FieldValueLanguage
dc.contributor.authorAllwood, Billy L.-
dc.contributor.authorSpencer, Neil-
dc.contributor.authorShahriari-Zavareh, Hooshang-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:14:08Z-
dc.date.available2023-10-06T05:14:08Z-
dc.date.issued1987-
dc.identifier.citationJournal of the Chemical Society, Chemical Communications, 1987, n. 14, p. 1061-1064-
dc.identifier.issn0022-4936-
dc.identifier.urihttp://hdl.handle.net/10722/332770-
dc.description.abstractX-Ray structural investigations of a bisparaphenylene-34-crown-10 derivative (BPP34C10) and its 1:1:1 complex with [Diquat][PF6] 2 and H2O reveal that, of two crystallographically independent conformations (I and II) both supporting large molecular cavities, one (II) retains its gross shape on complexation and interacts with the [Diquat]2+ dication by means of hydrogen and electrostatic bonds whilst accommodating weak charge transfer interactions and a hydrogen bonded H2O molecule within the docking constraints and microcavity, respectively, imposed by the more dominant non-covalent forces.-
dc.languageeng-
dc.relation.ispartofJournal of the Chemical Society, Chemical Communications-
dc.titleComplexation of Diquat by a bisparaphenylene-34-crown-10 derivative-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/C39870001061-
dc.identifier.scopuseid_2-s2.0-37049080891-
dc.identifier.issue14-
dc.identifier.spage1061-
dc.identifier.epage1064-
dc.identifier.isiWOS:A1987J524400007-

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